Enantioselective total synthesis of clavirolide C. Applications of Cu-catalyzed asymmetric conjugate additions and Ru-catalyzed ring-closing metathesis.
about
Conformational effects and stereocontrol in synthesis studies of medium-ring dolabellane carbocycles.Strained cyclophane macrocycles: impact of progressive ring size reduction on synthesis and structureCatalytic enantioselective synthesis of quaternary carbon stereocentresDirect synthesis of medium-bridged twisted amides via a transannular cyclization strategyC-C bond formation via copper-catalyzed conjugate addition reactions to enones in water at room temperatureRuthenium-Catalyzed Metathesis Cascade Reactions in Natural Products Synthesis.Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications.Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity.A multicomponent Ni-, Zr-, and Cu-catalyzed strategy for enantioselective synthesis of alkenyl-substituted quaternary carbons.Quaternary carbon stereogenic centers through copper-catalyzed enantioselective allylic substitutions with readily accessible aryl- or heteroaryllithium reagents and aluminum chlorides.N-Substituted tertiary and O-substituted quaternary carbon stereogenic centers by site-, diastereo- and enantioselective vinylogous Mannich reactions.Stereogenic-at-metal Zn- and Al-based N-heterocyclic carbene (NHC) complexes as bifunctional catalysts in Cu-free enantioselective allylic alkylations.Design and stereoselective preparation of a new class of chiral olefin metathesis catalysts and application to enantioselective synthesis of quebrachamine: catalyst development inspired by natural product synthesis.Vicinal diboronates in high enantiomeric purity through tandem site-selective NHC-Cu-catalyzed boron-copper additions to terminal alkynes.Enantioselective synthesis of allylboronates bearing a tertiary or quaternary B-substituted stereogenic carbon by NHC-Cu-catalyzed substitution reactions.Enantioselective synthesis of quaternary carbon stereogenic centers through copper-catalyzed conjugate additions of aryl- and alkylaluminum reagents to acyclic trisubstituted enonesAcyclic quaternary centers from asymmetric conjugate addition of alkylzirconium reagents to linear trisubstituted enones.Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.Formation of vinyl-, vinylhalide- or acyl-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed enantioselective conjugate additions of Si-containing vinylaluminums to β-substituted cyclic enones.Metal-free catalytic C-Si bond formation in an aqueous medium. Enantioselective NHC-catalyzed silyl conjugate additions to cyclic and acyclic α,β-unsaturated carbonyls.Formation of quaternary centers by copper-catalyzed asymmetric conjugate addition of alkylzirconium reagents.Copper-catalyzed asymmetric conjugate addition of alkylzirconium reagents to cyclic enones to form quaternary centers.A 12-membered to a strained 11-membered ring: first stereoselective total synthesis of (-)-asteriscunolide C.Rhodium(I)-Complexes Catalyzed 1,4-Conjugate Addition of Arylzinc Chlorides to N-Boc-4-pyridone.Conference Report: ESF-COST High-Level Research Conference Natural Products Chemistry, Biology and Medicine III.
P2860
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P2860
Enantioselective total synthesis of clavirolide C. Applications of Cu-catalyzed asymmetric conjugate additions and Ru-catalyzed ring-closing metathesis.
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年学术文章
@wuu
2008年学术文章
@zh
2008年学术文章
@zh-cn
2008年学术文章
@zh-hans
2008年学术文章
@zh-my
2008年学术文章
@zh-sg
2008年學術文章
@yue
2008年學術文章
@zh-hant
name
Enantioselective total synthes ...... lyzed ring-closing metathesis.
@en
Enantioselective total synthes ...... lyzed ring-closing metathesis.
@nl
type
label
Enantioselective total synthes ...... lyzed ring-closing metathesis.
@en
Enantioselective total synthes ...... lyzed ring-closing metathesis.
@nl
prefLabel
Enantioselective total synthes ...... lyzed ring-closing metathesis.
@en
Enantioselective total synthes ...... lyzed ring-closing metathesis.
@nl
P2860
P356
P1476
Enantioselective total synthes ...... lyzed ring-closing metathesis.
@en
P2093
Amir H Hoveyda
M Kevin Brown
P2860
P304
12904-12906
P356
10.1021/JA8058414
P407
P577
2008-09-09T00:00:00Z