Iron-catalyzed cyclopropanation with trifluoroethylamine hydrochloride and olefins in aqueous media: in situ generation of trifluoromethyl diazomethane.
about
Copper-Catalyzed Aerobic C-H Trifluoromethylation of Phenanthrolines.New Approaches to the Synthesis of Metal Carbenes.Fluorinated diazoalkanes - a versatile class of reagents for the synthesis of fluorinated compounds.Recent Progress Toward the Synthesis of Trifluoromethyl- and Difluoromethyl-Substituted Cyclopropanes.Synthesis and applications of α-trifluoromethylated alkylboron compoundsSynthesis of trifluoromethylated isoxazolidines: 1,3-dipolar cycloaddition of nitrosoarenes, (trifluoromethyl)diazomethane, and alkenes.Copper(II)-catalyzed trifluoromethylation of N-aryl imines.Reaction of trisubstituted alkenes with iron porphyrin carbenes: facile synthesis of tetrasubstituted dienes and cyclopentadienes.Copper-catalyzed trifluoromethylation-cyclization of enynes: highly regioselective construction of trifluoromethylated carbocycles and heterocycles.Reactions of iron carbenes with α,β-unsaturated esters by using an Umpolung approach: mechanism and applications.Difluoromethylcarbene for iron-catalyzed cyclopropanation.Batch and Continuous-Flow One-Pot Processes using Amine Diazotization to Produce Silylated Diazo Reagents.Highly Diastereo- and Enantioselective Synthesis of Trifluoromethyl-Substituted Cyclopropanes via Myoglobin-Catalyzed Transfer of Trifluoromethylcarbene.Highly efficient "on water" catalyst-free nucleophilic addition reactions using difluoroenoxysilanes: dramatic fluorine effects.Use of a Traceless Activating and Directing Group for the Construction of Trifluoromethylpyrazoles: One-Pot Transformation of Nitroolefins and Trifluorodiazoethane.The asymmetric synthesis of CF3-containing spiro[pyrrolidin-3,2'-oxindole] through the organocatalytic 1,3-dipolar cycloaddition reaction.Silver(I)-Catalyzed N-Trifluoroethylation of Anilines and O-Trifluoroethylation of Amides with 2,2,2-Trifluorodiazoethane.Continuous in situ generation, separation, and reaction of diazomethane in a dual-channel microreactor.Copper-catalyzed one-pot denitrogenative-dehydrogenative-decarboxylative coupling of β-ketoacids with trifluorodiazoethane: facile access to trifluoromethylated aldol products.Three-component synthesis of fluorinated pyrazoles from fluoroalkylamines, NaNO2 and electron-deficient alkynes.Synthesis, characterisation and catalytic use of iron porphyrin amino ester conjugates
P2860
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P2860
Iron-catalyzed cyclopropanation with trifluoroethylamine hydrochloride and olefins in aqueous media: in situ generation of trifluoromethyl diazomethane.
description
2010 nî lūn-bûn
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2010年の論文
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2010年学术文章
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2010年学术文章
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2010年学术文章
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2010年学术文章
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2010年学术文章
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2010年學術文章
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name
Iron-catalyzed cyclopropanatio ...... trifluoromethyl diazomethane.
@en
Iron-catalyzed cyclopropanatio ...... trifluoromethyl diazomethane.
@nl
type
label
Iron-catalyzed cyclopropanatio ...... trifluoromethyl diazomethane.
@en
Iron-catalyzed cyclopropanatio ...... trifluoromethyl diazomethane.
@nl
prefLabel
Iron-catalyzed cyclopropanatio ...... trifluoromethyl diazomethane.
@en
Iron-catalyzed cyclopropanatio ...... trifluoromethyl diazomethane.
@nl
P2860
P356
P1476
Iron-catalyzed cyclopropanatio ...... trifluoromethyl diazomethane.
@en
P2093
Bill Morandi
P2860
P304
P356
10.1002/ANIE.200905573
P407
P577
2010-01-01T00:00:00Z