New N-heterocyclic carbene ligand and its application in asymmetric nickel-catalyzed aldehyde/alkyne reductive couplings.
about
Macrocyclization by nickel-catalyzed, ester-promoted, epoxide-alkyne reductive coupling: total synthesis of (-)-gloeosporone.Mechanism and transition-state structures for nickel-catalyzed reductive alkyne-aldehyde coupling reactions.Origins of regioselectivity and alkene-directing effects in nickel-catalyzed reductive couplings of alkynes and aldehydesNickel-Catalyzed Coupling Reactions of AlkenesA new biarylphosphine ligand for the Pd-catalyzed synthesis of diaryl ethers under mild conditions.Formation of C-C bonds via ruthenium-catalyzed transfer hydrogenation().The regio- and stereochemical course of reductive cross-coupling reactions between 1,3-disubstituted allenes and vinylsilanes: Synthesis of (Z)-dienes.Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.A streamlined strategy for aglycone assembly and glycosylation.Regioselective Reductive Cross-Coupling Reactions of Unsymmetrical Alkynes.Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.A convergent route to the CDEF-tetracycle of pectenotoxin-2.Alkyne-aldehyde reductive C-C coupling through ruthenium-catalyzed transfer hydrogenation: direct regio- and stereoselective carbonyl vinylation to form trisubstituted allylic alcohols in the absence of premetallated reagents.Enantioselective conjugate silyl additions to cyclic and acyclic unsaturated carbonyls catalyzed by Cu complexes of chiral N-heterocyclic carbenesA general strategy for regiocontrol in nickel-catalyzed reductive couplings of aldehydes and alkynes.Two-step synthesis of chiral fused tricyclic scaffolds from phenols via desymmetrization on nickel.Diastereoselective Nickel-Catalyzed Reductive Couplings of Aminoaldehydes and Alkynylsilanes: Application to the Synthesis of D-erythro-Sphingosine.Breaking Amides using Nickel Catalysis.Efficient boron-copper additions to aryl-substituted alkenes promoted by NHC-based catalysts. enantioselective Cu-catalyzed hydroboration reactions.Metallacycle-Mediated Cross-Coupling in Natural Product Synthesis.Catalytic enantioselective synthesis of α-substituted secondary allylic alcohols from terminal alkynes and aldehydes via vinylaluminum reagents.Triptycene-Based Chiral and meso-N-Heterocyclic Carbene Ligands and Metal Complexes.NHC Ligands Tailored for Simultaneous Regio- and Enantiocontrol in Nickel-Catalyzed Reductive Couplings.Enantioselective NiH/Pmrox-Catalyzed 1,2-Reduction of α,β-Unsaturated Ketones.Aldehydes as alkyl carbanion equivalents for additions to carbonyl compounds.Nickel(0)-catalyzed intramolecular reductive coupling of alkenes and aldehydes or ketones with hydrosilanes.Diboron as a reductant for nickel-catalyzed reductive coupling: rational design and mechanistic studies.
P2860
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P2860
New N-heterocyclic carbene ligand and its application in asymmetric nickel-catalyzed aldehyde/alkyne reductive couplings.
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年学术文章
@wuu
2007年学术文章
@zh
2007年学术文章
@zh-cn
2007年学术文章
@zh-hans
2007年学术文章
@zh-my
2007年学术文章
@zh-sg
2007年學術文章
@yue
2007年學術文章
@zh-hant
name
New N-heterocyclic carbene lig ...... de/alkyne reductive couplings.
@en
New N-heterocyclic carbene lig ...... de/alkyne reductive couplings.
@nl
type
label
New N-heterocyclic carbene lig ...... de/alkyne reductive couplings.
@en
New N-heterocyclic carbene lig ...... de/alkyne reductive couplings.
@nl
prefLabel
New N-heterocyclic carbene lig ...... de/alkyne reductive couplings.
@en
New N-heterocyclic carbene lig ...... de/alkyne reductive couplings.
@nl
P2860
P356
P1476
New N-heterocyclic carbene lig ...... de/alkyne reductive couplings.
@en
P2093
Grant J Sormunen
Mani Raj Chaulagain
P2860
P304
P356
10.1021/JA072992F
P407
P577
2007-07-12T00:00:00Z