Catalytic asymmetric reductive coupling of alkynes and aldehydes: enantioselective synthesis of allylic alcohols and alpha-hydroxy ketones.
about
TriethylboraneMechanism and transition-state structures for nickel-catalyzed reductive alkyne-aldehyde coupling reactions.Origins of regioselectivity and alkene-directing effects in nickel-catalyzed reductive couplings of alkynes and aldehydesA single step approach to piperidines via Ni-catalyzed β-carbon elimination.An expeditious route to eight-membered heterocycles by nickel-catalyzed cycloaddition: low-temperature C(sp)2-C(sp)3 bond cleavageNickel-catalyzed cycloadditions of unsaturated hydrocarbons, aldehydes, and ketones.Total synthesis of (+)-acutiphycinTotal syntheses of amphidinolides T1 and T4 via catalytic, stereoselective, reductive macrocyclizationsNickel-Catalyzed Coupling Reactions of AlkenesFormation of C-C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition of Carbonyl Compounds and IminesNickel Catalysis: Synergy between Method Development and Total SynthesisFormation of C-C bonds via ruthenium-catalyzed transfer hydrogenation().anti-1,2-Diols via Ni-catalyzed reductive coupling of alkynes and alpha-oxyaldehydesCatalytic asymmetric generation of (Z)-disubstituted allylic alcoholsA reductive coupling strategy towards ripostatin A.The regio- and stereochemical course of reductive cross-coupling reactions between 1,3-disubstituted allenes and vinylsilanes: Synthesis of (Z)-dienes.Catalytic carbonyl addition through transfer hydrogenation: a departure from preformed organometallic reagents.One-pot multicomponent coupling methods for the synthesis of diastereo- and enantioenriched (Z)-trisubstituted allylic alcohols.Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis.Direct vinylation of alcohols or aldehydes employing alkynes as vinyl donors: a ruthenium catalyzed C-C bond-forming transfer hydrogenation.A convergent route to the CDEF-tetracycle of pectenotoxin-2.Methyl Complexes of the Transition Metals.Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges.Alkyne-aldehyde reductive C-C coupling through ruthenium-catalyzed transfer hydrogenation: direct regio- and stereoselective carbonyl vinylation to form trisubstituted allylic alcohols in the absence of premetallated reagents.Synthesis and Characterization of Dimethylbis(2-pyridyl)borate Nickel(II) Complexes: Unimolecular Square-Planar to Square-Planar Rotation around Nickel(II)1,1-Disubstituted olefin synthesis via Ni-catalyzed Markovnikov hydroalkylation of alkynes with alkyl halides.Nickel-catalyzed regiodivergent opening of epoxides with aryl halides: co-catalysis controls regioselectivity.Diastereoselective Nickel-Catalyzed Reductive Couplings of Aminoaldehydes and Alkynylsilanes: Application to the Synthesis of D-erythro-Sphingosine.A surprising mechanistic "switch" in Lewis acid activation: a bifunctional, asymmetric approach to alpha-hydroxy acid derivativesSynthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.Breaking Amides using Nickel Catalysis.Strategic use of nickel(0)-catalyzed enyne-epoxide reductive coupling towards the synthesis of (-)-cyatha-3,12-diene.Hydroacylation of 2-Butyne from the Alcohol or Aldehyde Oxidation Level via Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation.Regioselectivity and enantioselectivity in nickel-catalysed reductive coupling reactions of alkynes.Stereoisomerically pure trisubstituted vinylaluminum reagents and their utility in copper-catalyzed enantioselective synthesis of 1,4-dienes containing Z or E alkenes.An alkoxide-directed intermolecular [2+2+1] annulation: a three-component coupling reaction for the synthesis of tetrasubstituted alpha,beta-unsaturated gamma-lactams.New N-heterocyclic carbene ligand and its application in asymmetric nickel-catalyzed aldehyde/alkyne reductive couplings.Metallacycle-Mediated Cross-Coupling in Natural Product Synthesis.Catalytic enantioselective synthesis of α-substituted secondary allylic alcohols from terminal alkynes and aldehydes via vinylaluminum reagents.
P2860
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P2860
Catalytic asymmetric reductive coupling of alkynes and aldehydes: enantioselective synthesis of allylic alcohols and alpha-hydroxy ketones.
description
2003 nî lūn-bûn
@nan
2003年の論文
@ja
2003年学术文章
@wuu
2003年学术文章
@zh
2003年学术文章
@zh-cn
2003年学术文章
@zh-hans
2003年学术文章
@zh-my
2003年学术文章
@zh-sg
2003年學術文章
@yue
2003年學術文章
@zh-hant
name
Catalytic asymmetric reductive ...... ols and alpha-hydroxy ketones.
@en
Catalytic asymmetric reductive ...... ols and alpha-hydroxy ketones.
@nl
type
label
Catalytic asymmetric reductive ...... ols and alpha-hydroxy ketones.
@en
Catalytic asymmetric reductive ...... ols and alpha-hydroxy ketones.
@nl
prefLabel
Catalytic asymmetric reductive ...... ols and alpha-hydroxy ketones.
@en
Catalytic asymmetric reductive ...... ols and alpha-hydroxy ketones.
@nl
P2093
P356
P1476
Catalytic asymmetric reductive ...... ols and alpha-hydroxy ketones.
@en
P2093
Karen M Miller
Timothy F Jamison
Wei-Sheng Huang
P304
P356
10.1021/JA034366Y
P407
P577
2003-03-01T00:00:00Z