An altered mechanism of hydrolysis for a metal-complexed phosphate diester.
about
Biological phosphoryl-transfer reactions: understanding mechanism and catalysisPhosphate forms an unusual tripodal complex with the Fe-Mn center of sweet potato purple acid phosphatase.Probing enzyme phosphoester interactions by combining mutagenesis and chemical modification of phosphate ester oxygens.Experimental analyses of the chemical dynamics of ribozyme catalysisMechanism and transition state structure of aryl methylphosphonate esters doubly coordinated to a dinuclear cobalt(III) center.Identification of catalytic metal ion ligands in ribozymes.Spectroscopic and mechanistic studies of dinuclear metallohydrolases and their biomimetic complexes.Integration of kinetic isotope effect analyses to elucidate ribonuclease mechanism.Catecholase activity, DNA cleavage and cytotoxicity of six Zn(II) complexes synthesized from designed Mannich ligands: higher reactivity of mononuclear over dinuclear.Kinetic isotope effects for RNA cleavage by 2'-O- transphosphorylation: nucleophilic activation by specific base.The effects of sulfur substitution for the nucleophile and bridging oxygen atoms in reactions of hydroxyalkyl phosphate esters.Altered transition state for the reaction of an RNA model catalyzed by a dinuclear zinc(II) catalyst.Efficient hydrolytic cleavage of plasmid DNA by chloro-cobalt(II) complexes based on sterically hindered pyridyl tripod tetraamine ligands: synthesis, crystal structure and DNA cleavage.Molybdenum carbonyl complexes with pyridylimino acidato ligands.Mechanistic investigation of the cleavage of phosphodiester catalyzed by a symmetrical oxyimine-based macrocyclic dinuclear zinc complex: a DFT study.
P2860
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P2860
An altered mechanism of hydrolysis for a metal-complexed phosphate diester.
description
2002 nî lūn-bûn
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2002年の論文
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2002年学术文章
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2002年学术文章
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2002年学术文章
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2002年學術文章
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name
An altered mechanism of hydrolysis for a metal-complexed phosphate diester.
@en
An altered mechanism of hydrolysis for a metal-complexed phosphate diester.
@nl
type
label
An altered mechanism of hydrolysis for a metal-complexed phosphate diester.
@en
An altered mechanism of hydrolysis for a metal-complexed phosphate diester.
@nl
prefLabel
An altered mechanism of hydrolysis for a metal-complexed phosphate diester.
@en
An altered mechanism of hydrolysis for a metal-complexed phosphate diester.
@nl
P50
P356
P1476
An altered mechanism of hydrolysis for a metal-complexed phosphate diester
@en
P2093
Tim Humphry
P304
14860-14861
P356
10.1021/JA027671C
P407
P577
2002-12-01T00:00:00Z