A highly efficient preparative method of alpha-ylidene-beta-diketones via Au(III)-catalyzed acyl migration of propargylic esters.
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Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent "gold rush"Mechanistically diverse copper-, silver-, and gold-catalyzed acyloxy and phosphatyloxy migrations: efficient synthesis of heterocycles via cascade migration/cycloisomerization approach.Metal-catalyzed double migratory cascade reactions of propargylic esters and phosphatesGold-catalyzed double migration-benzannulation cascade toward naphthalenes.Mechanistic studies on Au(I)-catalyzed [3,3]-sigmatropic rearrangements using cyclopropane probes.Gold(I)-catalyzed synthesis of (1E,3E)-dienes from propargylic esters.Ligand effects in homogeneous Au catalysis.Scope and Mechanistic Investigations on the Solvent-Controlled Regio- and Stereoselective Formation of Enol Esters from the Ruthenium-Catalyzed Coupling Reaction of Terminal Alkynes and Carboxylic Acids.Allenes and computational chemistry: from bonding situations to reaction mechanisms.Toward a symphony of reactivity: cascades involving catalysis and sigmatropic rearrangementsNazarov-like cyclization reactions.The use of Br/Cl to promote regioselective gold-catalyzed rearrangement of propargylic carboxylates: an efficient synthesis of (1Z, 3E)-1-bromo/chloro-2-carboxy-1,3-dienes.Triazole-Au(I) complex as chemoselective catalyst in promoting propargyl ester rearrangements.Pentannulation of Heterocycles by Virtue of Precious Metal Catalysis.Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: ligand-controlled regioselectivity.Substituent Effect on the Formation and Their Reactivity of Platinum Carbenoids.Gold-catalyzed regioselective oxidation of propargylic carboxylates: a reliable access to α-carboxy-α,β-unsaturated ketones/aldehydes.Rhodium-catalyzed carbonylation of cyclopropyl substituted propargyl esters: a tandem 1,3-acyloxy migration [5 + 1] cycloaddition.Highly efficient gold(I)-catalyzed Overman rearrangement in water.Electronic effects in the pt-catalyzed cycloisomerization of propargylic esters: synthesis of 2,3-disubstituted indolizines as a mechanistic probe.Complex alpha-pyrones synthesized by a gold-catalyzed coupling reaction.Syntheses of α-pyrones using gold-catalyzed coupling reactions.Gold-catalyzed regioselective oxidation of terminal allenes: formation of α-methanesulfonyloxy methyl ketones.Synthesis of highly functionalized cyclohexenone rings: rhodium-catalyzed 1,3-acyloxy migration and subsequent [5+1] cycloaddition.Gold(I)-catalyzed coupling reactions for the synthesis of diverse small molecules using the build/couple/pair strategy.Gold-catalyzed annulations of 2-alkynyl benzaldehydes with vinyl ethers: synthesis of dihydronaphthalene, isochromene, and bicyclo[2.2.2]octane derivatives.In situ generation of nucleophilic allenes by the gold-catalyzed rearrangement of propargylic esters for the highly diastereoselective formation of intermolecular C(sp3)-C(sp2) bonds.Gold-catalyzed tandem cycloisomerization and dimerization of chiral homopropargyl sulfonamides.Gold-catalyzed formal 1,6-acyloxy migration leading to 3,4-disubstituted pyrrolidin-2-ones.Gold(I)-catalyzed intramolecular hydroamination and ring-opening of sulfonamide-substituted 2-(arylmethylene)cyclopropylcarbinols.
P2860
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P2860
A highly efficient preparative method of alpha-ylidene-beta-diketones via Au(III)-catalyzed acyl migration of propargylic esters.
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年学术文章
@wuu
2006年学术文章
@zh-cn
2006年学术文章
@zh-hans
2006年学术文章
@zh-my
2006年学术文章
@zh-sg
2006年學術文章
@yue
2006年學術文章
@zh
2006年學術文章
@zh-hant
name
A highly efficient preparative method of alpha-ylidene-beta-diketones via Au
@nl
A highly efficient preparative ...... gration of propargylic esters.
@en
type
label
A highly efficient preparative method of alpha-ylidene-beta-diketones via Au
@nl
A highly efficient preparative ...... gration of propargylic esters.
@en
prefLabel
A highly efficient preparative method of alpha-ylidene-beta-diketones via Au
@nl
A highly efficient preparative ...... gration of propargylic esters.
@en
P356
P1476
A highly efficient preparative ...... igration of propargylic esters
@en
P2093
Shaozhong Wang
P304
P356
10.1021/JA062777J
P407
P50
P577
2006-07-01T00:00:00Z