Cu-catalyzed asymmetric allylic alkylations of aromatic and aliphatic phosphates with alkylzinc reagents. An effective method for enantioselective synthesis of tertiary and quaternary carbons.
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Synthesis of chiral mono(N-heterocyclic carbene) palladium and gold complexes with a 1,1'-biphenyl scaffold and their applications in catalysis.Enantioselective synthesis of α-aminosilanes by copper-catalyzed hydroamination of vinylsilanes.Ethylene in organic synthesis: a new route to anticholenergic pyrrolidinoindolines, and other molecules with all carbon-quaternary centers via asymmetric hydrovinylation.Divalent and Multivalent Activation in Phosphate Triesters: A Versatile Method for the Synthesis of Advanced Polyol Synthons.Mo-catalyzed regio-, diastereo-, and enantioselective allylic alkylation of 3-aryloxindoles.Three-component Ag-catalyzed enantioselective vinylogous mannich and Aza-Diels-Alder reactions with alkyl-substituted aldehydes(R)-3-METHYL-3-PHENYL-1-PENTENE VIA CATALYTIC ASYMMETRIC HYDROVINYLATION.Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.Quaternary carbon stereogenic centers through copper-catalyzed enantioselective allylic substitutions with readily accessible aryl- or heteroaryllithium reagents and aluminum chlorides.Scope and mechanism of formal S(N)2' substitution reactions of a monomeric imidozirconium complex with allylic electrophiles.Zirconium-mediated SN2' substitution of allylic ethers: regio- and stereospecific formation of protected allylic aminesStereogenic-at-metal Zn- and Al-based N-heterocyclic carbene (NHC) complexes as bifunctional catalysts in Cu-free enantioselective allylic alkylations.Enantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling.Enantioselective semireduction of allenes.A dual-catalysis approach to enantioselective [2 + 2] photocycloadditions using visible light.Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Tunable Phosphoramidite Ligands for Asymmetric Hydrovinylation: Ligands par excellence for Generation of All-Carbon Quaternary Centers.A novel catalytic asymmetric route towards skipped dienes with a methyl-substituted central stereogenic carbon.Iridium-catalyzed enantioselective allylic alkynylation.Bidentate hydroxyalkyl NHC ligands for the copper-catalyzed asymmetric allylic substitution of allyl phosphates with Grignard reagents.Copper-catalyzed regioselective fluorination of allylic halides.Photocatalytic Aerobic Phosphatation of Alkenes.Stereospecific, Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Allylic Pivalates To Deliver Quaternary Stereocenters.Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis.Synthesis of Branched Alkylboronates by Copper-Catalyzed Allylic Substitution Reactions of Allylic Chlorides with 1,1-Diborylalkanes.
P2860
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P2860
Cu-catalyzed asymmetric allylic alkylations of aromatic and aliphatic phosphates with alkylzinc reagents. An effective method for enantioselective synthesis of tertiary and quaternary carbons.
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年学术文章
@wuu
2004年学术文章
@zh-cn
2004年学术文章
@zh-hans
2004年学术文章
@zh-my
2004年学术文章
@zh-sg
2004年學術文章
@yue
2004年學術文章
@zh
2004年學術文章
@zh-hant
name
Cu-catalyzed asymmetric allyli ...... rtiary and quaternary carbons.
@en
Cu-catalyzed asymmetric allyli ...... rtiary and quaternary carbons.
@nl
type
label
Cu-catalyzed asymmetric allyli ...... rtiary and quaternary carbons.
@en
Cu-catalyzed asymmetric allyli ...... rtiary and quaternary carbons.
@nl
prefLabel
Cu-catalyzed asymmetric allyli ...... rtiary and quaternary carbons.
@en
Cu-catalyzed asymmetric allyli ...... rtiary and quaternary carbons.
@nl
P356
P1476
Cu-catalyzed asymmetric allyli ...... rtiary and quaternary carbons.
@en
P2093
Amir H Hoveyda
Monica A Kacprzynski
P304
10676-10681
P356
10.1021/JA0478779
P407
P577
2004-09-01T00:00:00Z