Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.
about
Recent advances in copper-catalyzed asymmetric coupling reactionsEnantioselective construction of remote quaternary stereocentresMultifunctional organoboron compounds for scalable natural product synthesis.Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsPalladium-catalyzed enantioselective Heck alkenylation of acyclic alkenols using a redox-relay strategy.Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary StereocentersEnantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers.New advances in dual stereocontrol for asymmetric reactions.A broadly applicable NHC-Cu-catalyzed approach for efficient, site-, and enantioselective coupling of readily accessible (pinacolato)alkenylboron compounds to allylic phosphates and applications to natural product synthesis.C-C bond formation via copper-catalyzed conjugate addition reactions to enones in water at room temperatureCopper-Catalyzed Transformations Using Cu-H, Cu-B, and Cu-Si as Active Catalyst Species.Catalytic SN2'- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis.NHC-Cu-catalyzed protoboration of monosubstituted allenes. Ligand-controlled site selectivity, application to synthesis and mechanism.Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity.Enantioselective Nickel-Catalyzed Intramolecular Allylic Alkenylations Enabled by Reversible Alkenylnickel E/Z Isomerization.Catalytic enantioselective allyl-allyl cross-coupling with a borylated allylboronate.Palladium-Catalyzed Oxidative Carbocyclization-Borylation of Enallenes to Cyclobutenes.Stereospecific Cross Couplings To Set Benzylic, All-Carbon Quaternary Stereocenters in High Enantiopurity.Enantioselective copper catalysed, direct functionalisation of allenes via allyl copper intermediates.Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents.Catalytic Borylative Opening of Propargyl Cyclopropane, Epoxide, Aziridine, and Oxetane Substrates: Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates.Metal-free catalytic enantioselective C-B bond formation: (pinacolato)boron conjugate additions to α,β-unsaturated ketones, esters, Weinreb amides, and aldehydes promoted by chiral N-heterocyclic carbenes.Combining NHC-Cu and Brønsted base catalysis: enantioselective allylic substitution/conjugate additions with alkynylaluminum reagents and stereospecific isomerization of the products to trisubstituted allenes.Enantioselective Generation of Adjacent Stereocenters in a Copper-Catalyzed Three-Component Coupling of Imines, Allenes, and DiboranesCu-catalyzed chemoselective preparation of 2-(pinacolato)boron-substituted allylcopper complexes and their in situ site-, diastereo-, and enantioselective additions to aldehydes and ketones.A robust, efficient, and highly enantioselective method for synthesis of homopropargyl aminesHighly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion.Enantioselective synthesis of boron-substituted quaternary carbon stereogenic centers through NHC-catalyzed conjugate additions of (pinacolato)boron units to enones.Amide-controlled highly selective catalytic borylcupration of allenes.Copper-catalyzed borylation of α-alkoxy allenes with bis(pinacolato)diboron: efficient synthesis of 2-boryl 1,3-butadienes.Anionic and zwitterionic copper(I) complexes incorporating an anionic N-heterocyclic carbene decorated with a malonate backbone: synthesis, structure and catalytic applications.Copper-catalyzed regioselective fluorination of allylic halides.Exceptionally E- and β-selective NHC-Cu-catalyzed proto-silyl additions to terminal alkynes and site- and enantioselective proto-boryl additions to the resulting vinylsilanes: synthesis of enantiomerically enriched vicinal and geminal borosilanes.Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.Construction of quaternary stereogenic carbon centers through copper-catalyzed enantioselective allylic cross-coupling with alkylboranes.NHC Ligands Tailored for Simultaneous Regio- and Enantiocontrol in Nickel-Catalyzed Reductive Couplings.Enantioselective Formation of CF3-Bearing All-Carbon Quaternary Stereocenters via C-H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation.Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis.Versatile Homoallylic Boronates by Chemo-, SN 2'-, Diastereo- and Enantioselective Catalytic Sequence of Cu-H Addition to Vinyl-B(pin)/Allylic Substitution.Enantioselective Synthesis of Trisubstituted Allenyl-B(pin) Compounds by Phosphine-Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu-Allenyl Intermediates.
P2860
Q26770614-48E7E880-BEF9-45F9-B741-9C9984ACF119Q33554259-DEA4DC42-91A8-4864-8BF5-84FE73C9A50CQ34712211-6645EE45-A58D-43C8-A0E1-C83C0C0397ACQ36049587-A2CDEF22-D8E7-4DC4-B8B2-445705E01265Q36671969-70E99510-1510-4565-98A2-6FD617ACD25EQ37289750-375FE2C9-7263-4B6A-B8DD-3389384A8C1AQ37494897-C85EA11F-E9E0-42CD-B08F-CA9C1BDF323FQ38099520-C78E2D1D-2A3E-475D-B23F-E77CEEDE406EQ38274670-CD769718-0FAE-49D4-BAA9-5016FA9D9EACQ38362852-17ED0D01-F4BE-4BE5-A648-9A2417F94877Q38887365-1A18579E-AD66-4D8D-B2C7-C7B55608B1B0Q39672627-5E841028-D836-4CC2-95ED-E6F847448DD4Q39834406-BB05B576-512D-4B24-9A9F-06AEF6AF904EQ40433430-0B48B9F4-492C-4472-BE6E-4C1F76C6E821Q40950927-8B770E15-C811-4A46-9597-3C8DCABF170BQ41034107-2F4DB58B-AC7C-4065-A0FB-7BC1F965A973Q41077764-F0A56D57-7595-41D9-A4D0-F5D2950C3F51Q41169168-AFB5BF72-2610-4291-A227-BAA70B642A2AQ41671020-1AC5E495-175F-446D-9C99-AB71A178E197Q41823171-E9EDECBB-3D5E-4D9D-A8B0-05011C629935Q41825369-C601FE93-0BF9-4FAE-BAB1-E4FA10A6BA56Q41826469-71A6C0A1-78C7-4711-861B-3DE68AFC7A8CQ41998174-0FD639CC-CD73-47F0-A194-E3F2C52A4FF4Q42075780-AAFC8375-C04A-40B9-B21F-22B01AFD41FFQ42133014-E8EC1CCA-190A-4FAA-A166-DD3EAD79E93DQ42182217-27EC06E5-DD69-4BF9-9BBF-5C557254ADC7Q42222494-15A85B60-D1C4-4B5A-A4DE-7C9173CA8EE3Q42732502-0DF69FA3-BBD7-4C7C-AB3F-0FF3299B637FQ43596487-AB6387D8-BA4E-4908-A51F-B6DFE4B4A2CCQ43826323-7B7A2B54-A45D-4B1E-81D5-4B7C06F9B917Q44275238-A8C9AF0D-CAC7-4452-BC03-10E8CC273431Q44295386-FCE9325A-E27B-4681-9EC2-F57B72788042Q46153547-EA82EC99-4C1B-424E-8D93-894FFB33AAC0Q46642667-47F32D4A-7663-406D-A769-D8F4AB81D835Q46914306-BF7863FF-D5CC-47EC-A97E-634A148607F5Q48267378-32865A12-7020-4C1B-B272-A90F7557C2F3Q48294382-3984D04A-1B51-442C-B02F-94E279930356Q48346593-FCC14EA4-90B5-4FD9-B6E8-8290C50345A5Q49369452-C1A4722B-7299-4DB2-8499-7AFDF0D2D934Q50124413-BBB36FC6-28C2-4ED4-95B2-7289381C12B4
P2860
Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
Site- and enantioselective for ...... atalyzed allylic substitution.
@en
type
label
Site- and enantioselective for ...... atalyzed allylic substitution.
@en
prefLabel
Site- and enantioselective for ...... atalyzed allylic substitution.
@en
P2860
P356
P1476
Site- and enantioselective for ...... atalyzed allylic substitution.
@en
P2093
Byunghyuck Jung
P2860
P304
P356
10.1021/JA211269W
P407
P577
2012-01-03T00:00:00Z