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The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total SynthesisFormal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation.Synthesis and Exploration of Electronically Modified (R)-5,5-Dimethyl-(p-CF3)3-i-PrPHOX in Palladium-Catalyzed Enantio- and Diastereoselective Allylic Alkylation: A Practical Alternative to (R)-(p-CF3)3-t-BuPHOX.Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketonesAdvances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters.A general enantioselective route to the chamigrene natural product family.Catalytic enantioselective approach to the eudesmane sesquiterpenoids: total synthesis of (+)-carissone.Enantioselective total synthesis of the reported structures of (-)-9-epi-presilphiperfolan-1-ol and (-)-presilphiperfolan-1-ol: structural confirmation and reassignment and biosynthetic insights.A unified approach to the daucane and sphenolobane bicyclo[5.3.0]decane core: enantioselective total syntheses of daucene, daucenal, epoxydaucenal B, and 14-para-anisoyloxydauc-4,8-diene.The catalytic enantioselective total synthesis of (+)-liphagal.Ring-contraction strategy for the practical, scalable, catalytic asymmetric synthesis of versatile γ-quaternary acylcyclopentenes.Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork-Danheiser approach: preparation of mono-, bi-, and tricyclic systems.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.The reaction mechanism of the enantioselective Tsuji allylation: inner-sphere and outer-sphere pathways, internal rearrangements, and asymmetric C-C bond formation.Enantioconvergent synthesis of (+)-aphanorphine via asymmetric Pd-catalyzed alkene carboamination.Assembly of the Limonoid Architecture by a Divergent Approach: Total Synthesis of (±)-Andirolide N via (±)-8α-Hydroxycarapin.
P2860
Q33763459-B0BA7F20-105F-49F4-9179-6168C04E942BQ34462839-6E82D270-6BD7-453A-8457-735AEFBE88B4Q35915688-03D6900E-7005-43B2-BAD9-8682D0014C02Q37274196-51A581CE-C951-4FD3-B34A-A96582C9742EQ39121643-FAC7EDAB-AAA2-48D5-91D6-25549D66D69BQ41136502-618C364B-66C3-40A3-B89C-BB0EAC10EDA5Q41788466-6DB87208-DB4F-445B-9B52-8F4BF58AB640Q41789456-9B721E15-BFA4-40ED-ACFC-742C43681CB9Q41865909-4F46C8C1-85D1-4787-99CE-D682B87B49A5Q41962514-4DDD2757-86F9-45A4-8171-949B70165D2AQ42179500-2A189046-46B8-4314-AA25-BDC1ADD07341Q42182827-ACA882A3-4AC0-4C79-A794-1380DAECA48FQ42182829-2765BA1A-771E-4981-8AC3-F13B47E4A560Q42182848-7FC8CA97-39F4-4207-86DB-AD0852A26B04Q42534222-7F66348E-911A-4505-995E-3E0CAE38F50EQ42744867-272AC1A5-222C-4513-935C-F5B8BACF4164Q48129232-EA62AECC-EE93-44B8-B204-EAA6C338E51F
P2860
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
@wuu
2009年学术文章
@zh
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
2009年学术文章
@zh-sg
2009年學術文章
@yue
2009年學術文章
@zh-hant
name
Enantioselective total synthesis of (+)-cassiol.
@en
type
label
Enantioselective total synthesis of (+)-cassiol.
@en
prefLabel
Enantioselective total synthesis of (+)-cassiol.
@en
P2860
P356
P1433
P1476
Enantioselective total synthesis of (+)-cassiol.
@en
P2093
Brian M Stoltz
Krastina V Petrova
P2860
P304
P356
10.1021/OL802410T
P407
P577
2009-01-01T00:00:00Z