Efficient boron-copper additions to aryl-substituted alkenes promoted by NHC-based catalysts. enantioselective Cu-catalyzed hydroboration reactions.
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Copper-catalyzed regioselective ortho C-H cyanation of vinylarenes.Multifunctional organoboron compounds for scalable natural product synthesis.Synthesis of chiral mono(N-heterocyclic carbene) palladium and gold complexes with a 1,1'-biphenyl scaffold and their applications in catalysis.Highly diastereo- and enantioselective CuH-catalyzed synthesis of 2,3-disubstituted indolinesCatalytic enantioselective olefin metathesis in natural product synthesis. Chiral metal-based complexes that deliver high enantioselectivity and moreRegio- and Stereospecific 1,3-Allyl Group Transfer Triggered by a Copper-Catalyzed Borylation/ortho-Cyanation Cascade.Enantio- and Diastereoselective 1,2-Additions to α-Ketoesters with Diborylmethane and Substituted 1,1-Diborylalkanes.Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si.Group-assisted purification (GAP) chemistry for the synthesis of Velcade via asymmetric borylation of N-phosphinylimines.Enantioselective conjugate silyl additions to cyclic and acyclic unsaturated carbonyls catalyzed by Cu complexes of chiral N-heterocyclic carbenesA catalytic enantiotopic-group-selective Suzuki reaction for the construction of chiral organoboronates.Amide-directed catalytic asymmetric hydroboration of trisubstituted alkenes.Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity.Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes.Diastereoselective Ni-catalyzed 1,4-hydroboration of chiral dienols.Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds.Kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via asymmetric Cu-catalyzed borylationRemarkable levels of enantioswitching in catalytic asymmetric hydroboration.Vicinal diboronates in high enantiomeric purity through tandem site-selective NHC-Cu-catalyzed boron-copper additions to terminal alkynes.Enantioselective synthesis of allylboronates bearing a tertiary or quaternary B-substituted stereogenic carbon by NHC-Cu-catalyzed substitution reactions.Enantioselective synthesis of boron-substituted quaternary carbons by NHC-Cu-catalyzed boronate conjugate additions to unsaturated carboxylic esters, ketones, or thioesters.2-[(Di-methyl-phenyl-phosphanyl-idene)aza-nium-yl]-5-methyl-benzene-sulfonate benzene monosolvate.Efficient C-B bond formation promoted by N-heterocyclic carbenes: synthesis of tertiary and quaternary B-substituted carbons through metal-free catalytic boron conjugate additions to cyclic and acyclic alpha,beta-unsaturated carbonyls.Enantioselective synthesis of homoallylic amines through reactions of (pinacolato)allylborons with aryl-, heteroaryl-, alkyl-, or alkene-substituted aldimines catalyzed by chiral C1-symmetric NHC-Cu complexes.Enantioselective synthesis of boron-substituted quaternary carbon stereogenic centers through NHC-catalyzed conjugate additions of (pinacolato)boron units to enones.Metal-free catalytic C-Si bond formation in an aqueous medium. Enantioselective NHC-catalyzed silyl conjugate additions to cyclic and acyclic α,β-unsaturated carbonyls.Diastereo- and enantioselective reactions of bis(pinacolato)diboron, 1,3-enynes, and aldehydes catalyzed by an easily accessible bisphosphine-Cu complex.Catalytic enantioselective protoboration of disubstituted allenes. Access to alkenylboron compounds in high enantiomeric purity.Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes.Bis(imidazoline-2-thione)-copper(I) catalyzed regioselective boron addition to internal alkynes.Exceptionally E- and β-selective NHC-Cu-catalyzed proto-silyl additions to terminal alkynes and site- and enantioselective proto-boryl additions to the resulting vinylsilanes: synthesis of enantiomerically enriched vicinal and geminal borosilanes.Mechanism-based enhancement of scope and enantioselectivity for reactions involving a copper-substituted stereogenic carbon centre.Copper-Catalyzed Oxyboration of Unactivated Alkenes.Enantioselective Borylative Dearomatization of Indoles through Copper(I) Catalysis.Copper-catalyzed asymmetric three-component borylstannation: enantioselective formation of C-Sn bond.Copper-catalyzed distannylation of alkynes.Copper-Catalyzed Enantioselective Markovnikov Protoboration of α-Olefins Enabled by a Buttressed N-Heterocyclic Carbene Ligand.Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Aliphatic Ketones: Synthesis of Enantioenriched Chiral Tertiary α-Hydroxyboronates.Catalytic diastereo- and enantioselective additions of versatile allyl groups to N-H ketimines.
P2860
Q34022018-FEDEEC15-1023-4A95-9254-9A520A622BAEQ34712211-312F7559-87B8-47F4-A546-C730DD4018CBQ35022496-AF98C606-6CB3-4A51-B7E5-8BCF44477E67Q35633975-90E1D92A-4064-4ACC-8EE5-744CEAA1C7E7Q36452747-1DA24CB6-FC32-4BA4-BB85-0449D3D14680Q36583181-42F49218-9EFB-498B-87E3-5AC234C2B0F8Q37209399-AE7354A2-5B4F-4720-934A-AC58628D0088Q38670368-110DF6FD-01C9-4108-B373-92FCAC90D7A0Q38967628-8A2306C4-8B65-41FB-B905-4D1A5EED9705Q39541733-A358A314-E3F5-4013-9349-865601B333E4Q39628761-5F960BC4-AE1B-4EE6-9E39-E75E038AAE81Q39826769-60673A0A-A3A5-4A13-AB6A-D1E19C258F2BQ40433430-308B8E33-2971-4363-97B7-465A36B88794Q40700153-BC081BE8-72FE-40A2-A2E6-E5E142540E69Q41048339-7ACD635C-D478-44E0-A55A-FE9A375E661AQ41087897-7E8BC65B-D1D6-4E45-8982-DF14B9725A7EQ41319490-354A9750-84F1-486B-919F-67821CEDEC0FQ41527801-9D3900BD-8210-4FDA-9C24-6B1B3921F23DQ41849452-F98DB504-A65A-4C74-BECA-6E3060708FA8Q41869714-097C4EB4-77EF-4E87-B568-82D6E487C6FCQ41917175-50006AF0-8386-4BC1-8EAB-4243AA1890A0Q42017401-10099D43-2B15-425B-8D7E-A2A3050A3CF1Q42160929-74A7A94B-50E6-43EA-997E-49B91D9337A4Q42563750-BC3A9FFC-5B13-44E5-A3B9-B5B2561634CDQ42697663-544FBEE3-0FED-4584-8C7C-5800F37C7EF7Q42732502-B79E8083-0E1C-499F-8028-76E74390A2E1Q42735961-DBC68AE6-872F-489C-BC67-A4D27E4C0B2CQ42828017-1D8433AA-399B-4CFE-B8A7-445CAF65EBFAQ42865603-C2D616A3-7ECC-42EF-9589-0209B63886C7Q42933893-9BA3D26C-C848-45F9-AC20-BE6A4D162B2FQ43189178-DB92849E-274B-42BE-9E2B-F075C6897EEEQ46153547-760203DD-10E2-4387-8C6E-F8A7D8624BC1Q46236790-64F812FF-FEAE-4FC6-A7D2-D44275720E95Q46668689-E9AAD11C-6B24-4954-BBB4-B7792352BA5FQ46712091-D2AA2060-16DA-42C9-96C2-9952F726024DQ46773283-391635F1-ADCF-4F73-A31B-9FC9185844EFQ46975501-3D132811-ADEE-4AEA-92A5-BE68EF1693F2Q48135982-8E456B83-F041-4315-95D5-8DE9EBF0247FQ48200533-7AD56360-DFAB-4159-81C1-40F60CA369D5Q48247687-07135F4C-FDB4-46E6-971F-EB1A9B50EDBE
P2860
Efficient boron-copper additions to aryl-substituted alkenes promoted by NHC-based catalysts. enantioselective Cu-catalyzed hydroboration reactions.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
@wuu
2009年学术文章
@zh
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
2009年学术文章
@zh-sg
2009年學術文章
@yue
2009年學術文章
@zh-hant
name
Efficient boron-copper additio ...... lyzed hydroboration reactions.
@en
Efficient boron-copper additio ...... lyzed hydroboration reactions.
@nl
type
label
Efficient boron-copper additio ...... lyzed hydroboration reactions.
@en
Efficient boron-copper additio ...... lyzed hydroboration reactions.
@nl
prefLabel
Efficient boron-copper additio ...... lyzed hydroboration reactions.
@en
Efficient boron-copper additio ...... lyzed hydroboration reactions.
@nl
P2860
P356
P1476
Efficient boron-copper additio ...... lyzed hydroboration reactions.
@en
P2093
P2860
P304
P356
10.1021/JA809382C
P407
P577
2009-03-01T00:00:00Z