Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile.
about
Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds.A Tale of Two Elements: The Lewis Acidity/Basicity Umpolung of Boron and Phosphorus.Borylenes: An Emerging Class of Compounds.1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres.Easy access to nucleophilic boron through diborane to magnesium boryl metathesis.Ambiphilic boron in 1,4,2,5-diazadiborinine.Borylation of fluorinated arenes using the boron-centred nucleophile B(CN)32- - a unique entry to aryltricyanoborates.Completing the series of boron-nucleophilic cyanoborates: boryl anions of type NHC-B(CN)2.A snapshot of inorganic Janovsky complex analogues featuring a nucleophilic boron center.Triaminotriborane(3): A Homocatenated Boron Chain Connected by B-B Multiple Bonds.From Borane to Borylene without Reduction: Ambiphilic Behavior of a Monovalent Silylisonitrile Boron Species.Carbones as Ligands in Novel Main-Group Compounds E[C(NHC)2 ]2 (E=Be, B+ , C2+ , N3+ , Mg, Al+ , Si2+ , P3+ ): A Theoretical Study.Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square.Interactions of Isonitriles with Metal-Boron Bonds: Insertions, Coupling, Ring Formation, and Liberation of Monovalent Boron.Serendipitous Observation of Al(I) Insertion into a CO Bond in L2 PhB: (L=oxazol-2-ylidene).Carbene-induced synthesis of the first borironium cations using the [(η(5)-C5Me5)Fe(CO)2](-) anion as an unlikely leaving group.The synthesis and structure of a carbene-stabilized iminocarboranyl-boron(I) compound.Multiple complexation of CO and related ligands to a main-group element.Diverse reactivity of a tricoordinate organoboron L2PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors.A DFT Study on the Stabilization of the B≡B Triple Bond in a Metallaborocycle: Contrasting Electronic Structures of Boron and Carbon Analogues.Ambireactive (R3 P)2 BH2 Groups Facilitating Temperature-Switchable Bond Activation by an Iron Complex.Phosphine-Stabilized Borylenes and Boryl Anions as Ligands? Redox Reactivity in Boron-Based Pincer Complexes.Deprotonation of a Hydridoborate Anion.Azaborabutadienes: Synthesis by Metal-Free Carboboration of Nitriles and Utility as Building Blocks for B,N-Heterocycles.Cyclic (Amino)(Phosphonium Bora-Ylide)Silanone: A Remarkable Room-Temperature-Persistent Silanone.Isolable Boron Persulfide: Activation of Elemental Sulfur with a 2-Chloro-Azaborolyl Anion.Donor ligands based on tricoordinate boron formed by B-H-activation of bis(phosphine)boronium salts.Reduction of a diamidocarbene-supported borenium cation: isolation of a neutral boryl-substituted radical and a carbene-stabilized aminoborylene.Exceptionally Strong Electron-Donating Ability of Bora-Ylide Substituent vis-à-vis Silylene and Silylium Ion.The Lightest Element Phosphoranylidene: NHC-Supported Cyclic Borylidene-Phosphorane with Significant B=P Character.Donor-acceptor bonding in novel low-coordinated compounds of boron and group-14 atoms C-Sn.Trimetallaborides as starting points for the syntheses of large metal-rich molecular borides and clustersReversible [4 + 2] cycloaddition reaction of 1,3,2,5-diazadiborinine with ethylene.A redox-active diborane platform performs C(sp3)-H activation and nucleophilic substitution reactions.Eine Geschichte über zwei Elemente: die Umpolung der Lewis-Acidität/Basizität von Bor und PhosphorAnorganische Chemie 2014
P2860
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P2860
Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile.
description
2014 nî lūn-bûn
@nan
2014年の論文
@ja
2014年学术文章
@wuu
2014年学术文章
@zh
2014年学术文章
@zh-cn
2014年学术文章
@zh-hans
2014年学术文章
@zh-my
2014年学术文章
@zh-sg
2014年學術文章
@yue
2014年學術文章
@zh-hant
name
Isolation of a bis
@nl
Isolation of a bis(oxazol-2-yl ...... a boron-centered nucleophile.
@en
type
label
Isolation of a bis
@nl
Isolation of a bis(oxazol-2-yl ...... a boron-centered nucleophile.
@en
prefLabel
Isolation of a bis
@nl
Isolation of a bis(oxazol-2-yl ...... a boron-centered nucleophile.
@en
P2860
P50
P356
P1476
Isolation of a bis(oxazol-2-yl ...... a boron-centered nucleophile.
@en
P2093
P2860
P304
P356
10.1002/ANIE.201405201
P407
P577
2014-06-30T00:00:00Z