Primary Deuterium Kinetic Isotope Effects From Product Yields: Rationale, Implementation, and Interpretation.

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Orotidine 5'-Monophosphate Decarboxylase: Probing the Limits of the Possible for Enzyme Catalysis.

P2860

Q51732733-EF17C703-3A53-4FC4-9F80-C7518123D9AD

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Primary Deuterium Kinetic Isotope Effects From Product Yields: Rationale, Implementation, and Interpretation.

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2017 nî lūn-bûn

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2017年の論文

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2017年学术文章

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2017年学术文章

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2017年学术文章

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2017年学术文章

@zh-hans

2017年学术文章

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2017年学术文章

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2017年學術文章

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Primary Deuterium Kinetic Isot ...... mentation, and Interpretation.

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Primary Deuterium Kinetic Isot ...... mentation, and Interpretation.

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type

Item

label

Primary Deuterium Kinetic Isot ...... mentation, and Interpretation.

@en

Primary Deuterium Kinetic Isot ...... mentation, and Interpretation.

@nl

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Primary Deuterium Kinetic Isot ...... mentation, and Interpretation.

@en

Primary Deuterium Kinetic Isot ...... mentation, and Interpretation.

@nl

P1476

Primary Deuterium Kinetic Isot ...... mentation, and Interpretation.

@en

P2093

Tina L Amyes

http://www.w3.org/2001/XMLSchema#string

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Formation and stability of a vinyl carbanion at the active site of orotidine 5'-monophosphate decarboxylase: pKa of the C-6 proton of enzyme-bound UMP

Product deuterium isotope effect for orotidine 5'-monophosphate decarboxylase: evidence for the existence of a short-lived carbanion intermediate

Anatomy of a proficient enzyme: The structure of orotidine 5'-monophosphate decarboxylase in the presence and absence of a potential transition state analog

The crystal structure and mechanism of orotidine 5'-monophosphate decarboxylase

Catalytic proficiency: the unusual case of OMP decarboxylase

Proton transfer from C-6 of uridine 5'-monophosphate catalyzed by orotidine 5'-monophosphate decarboxylase: formation and stability of a vinyl carbanion intermediate and the effect of a 5-fluoro substituent

Activation of R235A mutant orotidine 5'-monophosphate decarboxylase by the guanidinium cation: effective molarity of the cationic side chain of Arg-235

Structure-reactivity effects on primary deuterium isotope effects on protonation of ring-substituted alpha-methoxystyrenes

Product deuterium isotope effects for orotidine 5'-monophosphate decarboxylase: effect of changing substrate and enzyme structure on the partitioning of the vinyl carbanion reaction intermediate.

The structural basis for the remarkable catalytic proficiency of orotidine 5'-monophosphate decarboxylase.

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163-177

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scholarly article

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10.1016/BS.MIE.2017.06.043

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English

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596

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P50

John P. Richard

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2017-08-23T00:00:00Z

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28911770

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P932

5638648

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Primary Deuterium Kinetic Isotope Effects From Product Yields: Rationale, Implementation, and Interpretation.

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P2860

P2860

Primary Deuterium Kinetic Isotope Effects From Product Yields: Rationale, Implementation, and Interpretation.

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P1433

P1476

P2093

P2860

P304

P31

P356

P407

P478

P50

P577

P698

P932

P356

P1433

P1476

P2093

P2860

P304

P31

P356

P407

P478

P50

P577

P698

P932