Isolation of a non-heteroatom-stabilized gold-carbene complex.
about
Gold(I) Carbenoids: On-Demand Access to Gold(I) Carbenes in SolutionSynthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes.Gold carbenes, gold-stabilized carbocations, and cationic intermediates relevant to gold-catalysed enyne cycloaddition.Rearrangement of a Transient Gold Vinylidene into Gold Carbenes.The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium-to-Gold Transmetalation.Quantitative assessment of the carbocation/carbene character of the gold-carbene bond.Evidencing an inner-sphere mechanism for NHC-Au(I)-catalyzed carbene-transfer reactions from ethyl diazoacetate.Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates.Gold carbene or carbenoid: is there a difference?On the Accessible Reaction Channels of Vinyl Gold(I) Species: π- and σ-Pathways.Gold-alkynyls in catalysis: alkyne activation, gold cumulenes and nuclearity.Methyl-, Ethenyl-, and Ethynyl-Bridged Cationic Digold Complexes Stabilized by Coordination to a Bulky Terphenylphosphine Ligand.Copper and Silver Carbene Complexes without Heteroatom-Stabilization: Structure, Spectroscopy, and Relativistic Effects.Redox-induced umpolung of transition metal carbenes.Catalytic α-Arylation of Imines Leading to N-Unprotected Indoles and Azaindoles.Gold-catalyzed para-selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds.A Nucleophilic Gold(III) Carbene Complex.Isolation of a Reactive Tricoordinate α-Oxo Gold Carbene Complex.Gold Catalysis for Heterocyclic Chemistry: A Representative Case Study on Pyrone Natural Products.Revealing the Activity of π-Acid Catalysts using a 7-Alkynyl Cycloheptatriene.Experimental Evaluation of (L)Au Electron-Donor Ability in Cationic Gold Carbene Complexes.Gold-catalysed facile access to indene scaffolds via sequential C-H functionalization and 5-endo-dig carbocyclization.Silver-Catalyzed Amidiniumation of Alkynes: Isolation of a Silver Intermediate, Synthesis of Enamine Amido Carbene Precursors, and an Unprecedented Umpolung of Propiolamide.Isolation of a Reactive Tricoordinate α-Oxo Gold Carbene ComplexA Nucleophilic Gold(III) Carbene Complex
P2860
Q37664031-17FE835A-1B07-43E5-A478-823EFC1EC68FQ37690244-7C0B12A7-1B94-4D8C-A0D2-52FD3D208A98Q38825967-11B839EA-B3B7-4441-9ECE-2554BFFB53ECQ38946542-8DE29204-39F2-4D9F-BFEF-A965B72614B7Q40214086-7DAFC5EE-9461-402A-92ED-60AACDA37971Q40751529-7B9E4EBC-7680-4495-913F-7B1DF15DA3E3Q41760899-4B24B7AC-3D06-4963-B58D-FF1251EC5AF1Q41962217-D8A7E891-D9FF-43C4-B111-02625AF6540BQ42128976-7C3D1A4C-8A36-4A88-B8AD-E511B6FD682DQ43170746-426CA5DE-2006-49F8-99B3-9996B20EF652Q46354325-333E8DD5-C771-49DA-A6F3-461EBD591463Q46516482-10B56140-FFD9-4245-8B3F-38FBDFCE3EE4Q46641167-1BD9DCCA-EED1-4EEA-9B3B-AB5902F1C6B0Q46698424-6AD292FA-0E58-405A-B863-4BB6CC331680Q47126956-0DBD44B8-B481-43B3-AA2C-C3AE36A5AFC0Q47145086-6973C3E1-5FFE-48AE-8E84-7123E899F96CQ47743567-399492AF-EA6B-4889-8F75-4F18C97A739FQ48056490-1C1CFE68-5A74-48A3-A22C-BB108F4EC7B4Q48125065-F48513D3-59B2-40BD-BCC6-ACC8D92204EFQ48141113-E59AAF8D-42CD-4DA5-AC4B-08A84DE9F28DQ48181749-91C01A53-B796-4B6A-A210-463BA4176C72Q48186694-AA73BFD0-F9E2-48E9-93FA-AE1C102C0CB2Q50224824-B29EF114-D914-430F-99E5-8A3D955E6F4CQ51683313-CF164A13-7510-4E0F-BEE2-A393D3C3AB94Q58447160-7BDAF27E-F0B8-4267-B294-57851AA20C9EQ59112760-0C8D3480-D783-4D45-A784-04E6BFE7723E
P2860
Isolation of a non-heteroatom-stabilized gold-carbene complex.
description
2014 nî lūn-bûn
@nan
2014年の論文
@ja
2014年学术文章
@wuu
2014年学术文章
@zh
2014年学术文章
@zh-cn
2014年学术文章
@zh-hans
2014年学术文章
@zh-my
2014年学术文章
@zh-sg
2014年學術文章
@yue
2014年學術文章
@zh-hant
name
Isolation of a non-heteroatom-stabilized gold-carbene complex.
@en
Isolation of a non-heteroatom-stabilized gold-carbene complex.
@nl
type
label
Isolation of a non-heteroatom-stabilized gold-carbene complex.
@en
Isolation of a non-heteroatom-stabilized gold-carbene complex.
@nl
prefLabel
Isolation of a non-heteroatom-stabilized gold-carbene complex.
@en
Isolation of a non-heteroatom-stabilized gold-carbene complex.
@nl
P2093
P2860
P356
P1476
Isolation of a non-heteroatom-stabilized gold-carbene complex.
@en
P2093
Bernd F Straub
Matthias W Hussong
Petra Krämer
P2860
P304
P356
10.1002/ANIE.201404032
P407
P577
2014-06-20T00:00:00Z