Gold(I)-catalyzed diazo cross-coupling: a selective and ligand-controlled denitrogenation/cyclization cascade.
about
Cycloaddition reactions of enoldiazo compounds.Gold-catalyzed oxidative couplings of two indoles with one aryldiazo cyanide under oxidant-free conditions.Recent Developments in Coinage Metal Catalyzed Transformations of Stabilized Vinyldiazo Compounds: Beyond Carbenic Pathways.N-Tosylhydrazones: versatile synthons in the construction of cyclic compounds.Divergent C-H Insertion-Cyclization Cascades of N-Allyl Ynamides.Cyclobutene vs 1,3-Diene Formation in the Gold-Catalyzed Reaction of Alkynes with Alkenes: The Complete Mechanistic Picture.Synthesis of Functionalized Cyclopentene Derivatives from Vinyldiazo Compounds and Vinylazides through Sequential Copper-Promoted [3+2] Cycloaddition/Azide Rearrangement.Gold-catalyzed para-selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds.Synthesis of seven-membered heterocycles via copper-catalyzed cross-coupling of terminal alkynes with diazo compounds and sequential Michael addition.Gold-catalyzed sequential annulations towards 3,4-fused bi/tri-cyclic furans involving a [3+2+2]-cycloaddition.Isolation of a Reactive Tricoordinate α-Oxo Gold Carbene Complex.Gold-catalyzed highly regio- and enantioselective vinylcarbene insertion into O-H bonds of 2-pyridones.Catalytic Enantioselective Synthesis of 2,5-Dihydrooxepines.Highly para-Selective C-H Alkylation of Benzene Derivatives with 2,2,2-Trifluoroethyl α-Aryl-α-Diazoesters.Catalytic Divergent [3+3]- and [3+2]-Cycloaddition by Discrimination Between Diazo Compounds.Gold-catalysed facile access to indene scaffolds via sequential C-H functionalization and 5-endo-dig carbocyclization.A controlled selective synthesis of dihydropyrans through tandem reaction of alkynes with diazo compounds.Gold/silver-catalyzed controllable regioselective vinylcarbene insertion into O-H bonds.Gold-Catalyzed Formal [4+1]/[4+3] Cycloadditions of Diazo Esters with Triazines.Stereodivergent Synthesis of N-Heterocycles by Catalyst-Controlled, Activity-Directed Tandem Annulation of Diazo Compounds with Amino Alkynes.Base-Promoted/Gold-Catalyzed Intramolecular Highly Selective and Controllable Detosylative Cyclization.Gold-catalyzed stereoselective dearomatization/metal-free aerobic oxidation: access to 3-substituted indolines/oxindoles.Origins of unique gold-catalysed chemo- and site-selective C–H functionalization of phenols with diazo compounds† †Electronic supplementary information (ESI) available: Data for new compounds, experimental procedures and theoretical studies on mechaIsolation of a Reactive Tricoordinate α-Oxo Gold Carbene Complex
P2860
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P2860
Gold(I)-catalyzed diazo cross-coupling: a selective and ligand-controlled denitrogenation/cyclization cascade.
description
2014 nî lūn-bûn
@nan
2014年の論文
@ja
2014年学术文章
@wuu
2014年学术文章
@zh-cn
2014年学术文章
@zh-hans
2014年学术文章
@zh-my
2014年学术文章
@zh-sg
2014年學術文章
@yue
2014年學術文章
@zh
2014年學術文章
@zh-hant
name
Gold(I)-catalyzed diazo cross- ...... ogenation/cyclization cascade.
@en
type
label
Gold(I)-catalyzed diazo cross- ...... ogenation/cyclization cascade.
@en
prefLabel
Gold(I)-catalyzed diazo cross- ...... ogenation/cyclization cascade.
@en
P2093
P2860
P356
P1476
Gold(I)-catalyzed diazo cross- ...... rogenation/cyclization cascade
@en
P2093
Chenghao Zhu
Guangyang Xu
P2860
P304
P356
10.1002/ANIE.201409845
P407
P50
P577
2014-11-10T00:00:00Z