Enantioselective reductive coupling of 1,3-enynes to heterocyclic aromatic aldehydes and ketones via rhodium-catalyzed asymmetric hydrogenation: mechanistic insight into the role of Brønsted acid additives.
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Cooperativity of regiochemistry control strategies in reductive couplings of propargyl alcohols and aldehydesOne-pot catalytic enantio- and diastereoselective syntheses of anti-, syn-cis-disubstituted, and syn-vinyl cyclopropyl alcoholsOrigins of regioselectivity and alkene-directing effects in nickel-catalyzed reductive couplings of alkynes and aldehydesEnantioselective iridium-catalyzed carbonyl allylation from the alcohol or aldehyde oxidation level via transfer hydrogenative coupling of allyl acetate: departure from chirally modified allyl metal reagents in carbonyl additionMechanism and origins of regio- and enantioselectivities in RhI-catalyzed hydrogenative couplings of 1,3-diynes and activated carbonyl partners: intervention of a cumulene intermediateFormation of C-C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition of Carbonyl Compounds and IminesEnantioselective C-H crotylation of primary alcohols via hydrohydroxyalkylation of butadieneCatalytic enantioselective olefin metathesis in natural product synthesis. Chiral metal-based complexes that deliver high enantioselectivity and moreFormation of C-C bonds via ruthenium-catalyzed transfer hydrogenation().The regio- and stereochemical course of reductive cross-coupling reactions between 1,3-disubstituted allenes and vinylsilanes: Synthesis of (Z)-dienes.Ligand effects in homogeneous Au catalysis.Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.Catalytic carbonyl addition through transfer hydrogenation: a departure from preformed organometallic reagents.Convergent synthesis of piperidines by the union of conjugated alkynes with imines: a unique regioselective bond construction for heterocycle synthesis.Highly Stereoselective Synthesis of Polycyclic Indoles through Rearrangement/[4+2] Cycloaddition under Sequential Catalysis.Regioselective Reductive Cross-Coupling Reactions of Unsymmetrical Alkynes.Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.Transfer hydrogenation with Hantzsch esters and related organic hydride donors.Catalytic selective synthesis.Asymmetric ion-pairing catalysis.Asymmetric counteranion-directed catalysis: concept, definition, and applications.Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis.Direct vinylation of alcohols or aldehydes employing alkynes as vinyl donors: a ruthenium catalyzed C-C bond-forming transfer hydrogenation.Formation of C-C Bonds via Ruthenium Catalyzed Transfer Hydrogenation: Carbonyl Addition from the Alcohol or Aldehyde Oxidation LevelMetallic organophosphates as catalysts in asymmetric synthesis: a return journey.Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges.Metal-catalyzed reductive coupling of olefin-derived nucleophiles: Reinventing carbonyl addition.Alkyne-aldehyde reductive C-C coupling through ruthenium-catalyzed transfer hydrogenation: direct regio- and stereoselective carbonyl vinylation to form trisubstituted allylic alcohols in the absence of premetallated reagents.Unlocking Hydrogenation for C-C Bond Formation: A Brief Overview of Enantioselective Methods.Enantioselective allylation, crotylation, and reverse prenylation of substituted isatins: iridium-catalyzed C-C bond-forming transfer hydrogenation.Redox-triggered C-C coupling of diols and alkynes: synthesis of β,γ-unsaturated α-hydroxyketones and furans by ruthenium-catalyzed hydrohydroxyalkylation.Carbonyl propargylation from the alcohol or aldehyde oxidation level employing 1,3-enynes as surrogates to preformed allenylmetal reagents: a ruthenium-catalyzed C-C bond-forming transfer hydrogenation.Diastereoselective Nickel-Catalyzed Reductive Couplings of Aminoaldehydes and Alkynylsilanes: Application to the Synthesis of D-erythro-Sphingosine.Palladium(II)/Brønsted Acid-Catalyzed Enantioselective Oxidative Carbocyclization-Borylation of Enallenes.Enantioselective α-vinylation of aldehydes via the synergistic combination of copper and amine catalysis.Ruthenium catalyzed hydrohydroxyalkylation of isoprene with heteroaromatic secondary alcohols: isolation and reversible formation of the putative metallacycle intermediate.Chiral-anion-dependent inversion of diastereo- and enantioselectivity in carbonyl crotylation via ruthenium-catalyzed butadiene hydrohydroxyalkylation.ESI-MS, DFT, and synthetic studies on the H(2)-mediated coupling of acetylene: insertion of C=X bonds into rhodacyclopentadienes and Brønsted acid cocatalyzed hydrogenolysis of organorhodium intermediates.anti-Aminoallylation of aldehydes via ruthenium-catalyzed transfer hydrogenative coupling of sulfonamido allenes: 1,2-aminoalcohols.New N-heterocyclic carbene ligand and its application in asymmetric nickel-catalyzed aldehyde/alkyne reductive couplings.
P2860
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P2860
Enantioselective reductive coupling of 1,3-enynes to heterocyclic aromatic aldehydes and ketones via rhodium-catalyzed asymmetric hydrogenation: mechanistic insight into the role of Brønsted acid additives.
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年学术文章
@wuu
2006年学术文章
@zh
2006年学术文章
@zh-cn
2006年学术文章
@zh-hans
2006年学术文章
@zh-my
2006年学术文章
@zh-sg
2006年學術文章
@yue
2006年學術文章
@zh-hant
name
Enantioselective reductive cou ...... le of Brønsted acid additives.
@en
Enantioselective reductive cou ...... le of Brønsted acid additives.
@nl
type
label
Enantioselective reductive cou ...... le of Brønsted acid additives.
@en
Enantioselective reductive cou ...... le of Brønsted acid additives.
@nl
prefLabel
Enantioselective reductive cou ...... le of Brønsted acid additives.
@en
Enantioselective reductive cou ...... le of Brønsted acid additives.
@nl
P356
P1476
Enantioselective reductive cou ...... le of Brønsted acid additives.
@en
P2093
Venukrishnan Komanduri
P304
16448-16449
P356
10.1021/JA0673027
P407
P577
2006-12-01T00:00:00Z