Palladium-Catalyzed Difluoroalkylation of Aryl Boronic Acids: A New Method for the Synthesis of Aryldifluoromethylated Phosphonates and Carboxylic Acid Derivatives
about
Palladium-catalyzed intramolecular C-H difluoroalkylation: synthesis of substituted 3,3-difluoro-2-oxindoles.A Visible-Light-Mediated Radical Smiles Rearrangement and its Application to the Synthesis of a Difluoro-Substituted Spirocyclic ORL-1 AntagonistCatalytic insertion of aldehydes into dihalonitroacetophenones via sequential bond scission-aldol reaction-acyl transfer.Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines.Mild silver-mediated geminal difluorination of styrenes using an air- and moisture-stable fluoroiodane reagent.Synthesis of Aryldifluoroamides by Copper-Catalyzed Cross-Coupling.Highly selective nickel-catalyzed gem-difluoropropargylation of unactivated alkylzinc reagents.Suzuki-Miyaura Cross-Coupling Reactions of Highly Fluorinated Arylboronic Esters: Catalytic Studies and Stoichiometric Model Reactions on the Transmetallation Step.Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone.MOF-Derived Cobalt Phosphide/Carbon Nanocubes for Selective Hydrogenation of Nitroarenes to Anilines.Copper-catalysed difluoroalkylation of aromatic aldehydes via a decarboxylation/aldol reaction.Copper/B2pin2-catalyzed C-H difluoroacetylation-cycloamidation of anilines leading to the formation of 3,3-difluoro-2-oxindoles.Palladium-catalyzed regioselective C-H fluoroalkylation of indoles at the C4-position.Direct Access to α,α-Difluoroacylated Arenes by Palladium-Catalyzed Carbonylation of (Hetero)Aryl Boronic Acid Derivatives.New Prospects toward the Synthesis of Difluoromethylated Phosphate Mimics.Regioselective synthesis of difluoroalkyl/perfluoroalkyl enones via Pd-catalyzed four-component carbonylative coupling reactions.Copper-Mediated Introduction of the CF2 PO(OEt)2 Motif: Scope and Limitations.Direct C-H difluoromethylenephosphonation of arenes and heteroarenes with bromodifluoromethyl phosphonate via visible-light photocatalysis.A Versatile Organocatalytic Approach for the Synthesis of Enantioenriched gem-Difluorinated Compounds.Synthesis of 1-Difluoroalkylated Isoquinolines via Palladium-Catalyzed Radical Cascade Difluoroalkylation-Cyclization of Vinyl Isocyanides with Bromodifluoroacetic Derivatives.Enhancement of neighbouring-group participation in Cu0-promoted cross-coupling gem-difluoromethylenation of aryl/alkenyl halides with 1,3-azolic difluoromethyl bromides.Geminal difunctionalization of α-diazo arylmethylphosphonates: synthesis of fluorinated phosphonates.Silver-catalyzed oxidative decarboxylation of difluoroacetates: efficient access to C-CF2 bond formation.Visible-Light Photoredox-Catalyzed C-H Difluoroalkylation of Hydrazones through an Aminyl Radical/Polar Mechanism.Copper-catalyzed olefinic C-H difluoroacetylation of enamides.Ag(i)-Catalyzed oxidative decarboxylation of difluoroacetates with activated alkenes to form difluorooxindoles.Selective difluoroalkylation of alkenes by using visible light photoredox catalysis.Visible light promoted carbodifluoroalkylation of allylic alcohols via concomitant 1,2-aryl migration.Developing the Saegusa-Ito Cyclisation for the Synthesis of Difluorinated Cyclohexenones.An efficient regioselective hydrodifluoromethylation of unactivated alkenes with TMSCF₂CO₂Et at ambient temperature.Highly effective copper-mediated gem-difluoromethylenation of arylboronic acids.Silver-catalyzed oxidative activation of benzylic C-H bonds for the synthesis of difluoromethylated arenes.Palladium-Catalyzed Remote Aryldifluoroalkylation of Alkenyl Aldehydes.Gold-Catalyzed Highly Selective Photoredox C(sp(2) )-H Difluoroalkylation and Perfluoroalkylation of Hydrazones.Recent Progress toward the Introduction of Functionalized Difluoromethylated Building Blocks onto C(sp(2) ) and C(sp) Centers.Carbonylation of Difluoroalkyl Bromides Catalyzed by PalladiumA General Synthesis of Fluoroalkylated Alkenes by Palladium-Catalyzed Heck-Type Reaction of Fluoroalkyl BromidesCopper-Catalyzed Innate Ethoxycarbonyldifluoromethylation of Electron-Rich ArenesCopper-Mediated Formation of Aryl, Heteroaryl, Vinyl and Alkynyl Difluoromethylphosphonates: A General Approach to Fluorinated Phosphate MimicsCopper-Mediated Synthesis of Aryldifluoromethylphosphonates: A Sandmeyer Approach
P2860
Q35259134-D1FE554C-4CD3-4DBD-94B3-F2DCED935E9EQ36497550-549E9EAA-5140-4D16-8BFF-0C93F1A6C13AQ36599036-3E56A2AA-65CF-4027-84D4-B479B8693F3FQ37733829-945270CD-2640-461B-8724-65FD6B722C0DQ41484335-FCE444F4-BFE0-46AD-9C9D-F6290BBB188EQ41972307-1FEF3CF3-ADD8-4831-A5F0-132EA7D0989EQ45469190-EC3CA5A7-762A-4DBD-8421-D7A9FE222821Q46403875-F1E9D50C-D3DB-46D2-A8EB-C255AA16F42BQ46599184-CED7E93C-F83D-4744-BC48-785DAD9C139EQ47229405-B04414D7-4980-40B3-A276-69C6ABAC4B00Q47717616-8F9E968C-7F80-45D7-87D5-29B219B25094Q48089434-D69DD9AF-B76A-4CF1-BDA0-D8BBC81D1F76Q48132804-ACD315BF-A9D4-40F2-B6C6-80FE46DC0FF9Q48185058-9BEF9379-CF63-4F0D-901A-5FC0296F816DQ48189806-79B3CA46-113C-4819-B8A2-3409E12BF540Q48218794-888B804A-E210-46BC-9D59-76EE723F755AQ48296016-64641C87-0140-4082-BDDA-4F76B4E69F61Q50220674-ECFF7B4D-1D47-4040-A4FB-6FBEDEC7D438Q50949236-B8291279-5493-4D71-8D78-EC23DEC57A74Q51049158-86F5E426-FBFE-4624-BAD1-14BB5601FB52Q51070416-257010B8-F191-4FB5-A193-BF690C780C6CQ51132694-05014599-0F65-4361-BE3F-D8810050C2C3Q51608254-E720633E-E71E-4CC5-A572-49A55D399471Q51635178-B149F9D4-54D3-4ADB-B0B6-7FE5C1D204FEQ51739937-73DE397A-B35D-4C1F-AA79-20B341529F93Q53222091-CC6DC45D-D372-44E3-83C4-E399DB62D65FQ53260634-EA9B2CA0-ABAB-4666-A12D-30F30EA785BBQ53281114-4A4216A1-2F13-4898-A50C-E2B7AF5FA7FDQ53285660-A06DD327-820F-4969-8AB3-0751A3E2A466Q53502459-1EDFB318-0C77-45CF-B634-6EB376002B8CQ53535879-DF941376-99AF-46C5-9586-56CA27B7464EQ53567080-E19FCFB5-42A9-4752-9D00-550EC66B5FEEQ53580214-D68BD1D1-DA97-42C4-8CB6-30CAD5465133Q53639764-D4426EDC-C290-43F5-9432-01F26A5861A9Q53810355-BCFCCCC5-B353-4511-A059-DD1773D47E73Q58803297-12B7348F-EACE-4D9D-83DD-DC7D06AEAAECQ58803304-9CFAF67F-5013-4C33-B23A-C0C07853E36CQ59071327-8CC8E79F-E54E-46CB-86DE-18CFBD162B78Q59071338-523B42EC-A629-4B47-97D0-71B134BC4EDDQ59071349-FDC3008A-BB4E-44F0-B657-F5654D10ADF9
P2860
Palladium-Catalyzed Difluoroalkylation of Aryl Boronic Acids: A New Method for the Synthesis of Aryldifluoromethylated Phosphonates and Carboxylic Acid Derivatives
description
scientific article published on 22 January 2014
@en
wetenschappelijk artikel
@nl
наукова стаття, опублікована в січні 2014
@uk
name
Palladium-Catalyzed Difluoroal ...... nd Carboxylic Acid Derivatives
@en
Palladium-Catalyzed Difluoroal ...... nd Carboxylic Acid Derivatives
@nl
type
label
Palladium-Catalyzed Difluoroal ...... nd Carboxylic Acid Derivatives
@en
Palladium-Catalyzed Difluoroal ...... nd Carboxylic Acid Derivatives
@nl
prefLabel
Palladium-Catalyzed Difluoroal ...... nd Carboxylic Acid Derivatives
@en
Palladium-Catalyzed Difluoroal ...... nd Carboxylic Acid Derivatives
@nl
P2093
P2860
P356
P1476
Palladium-catalyzed difluoroal ...... nd carboxylic acid derivatives
@en
P2093
Qiao-Qiao Min
Xingang Zhang
Yu-Lan Xiao
P2860
P304
P356
10.1002/ANIE.201309535
P407
P50
P577
2014-01-22T00:00:00Z