Structures and reactivities of O-methylated Breslow intermediates.
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Organocatalytic Reactions Enabled by N-Heterocyclic CarbenesUmpolung by N-Heterocyclic Carbenes: Generation and Reactivity of the Elusive 2,2-Diamino Enols (Breslow Intermediates)Intercepting the Breslow intermediate via Claisen rearrangement: synthesis of complex tertiary alcohols without organometallic reagents.Rate and equilibrium constants for the addition of N-heterocyclic carbenes into benzaldehydes: a remarkable 2-substituent effect.A quantitative approach to nucleophilic organocatalysis.Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect.NHC-catalyzed hydroacylation of styrenes.Characterization of the key intermediates of carbene-catalyzed umpolung by NMR spectroscopy and X-ray diffraction: breslow intermediates, homoenolates, and azolium enolates.Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes.NHC-catalysed benzoin condensation - is it all down to the Breslow intermediate?Highly chemoselective intermolecular cross-benzoin reactions using an ad hoc designed novel N-heterocyclic carbene catalyst.Oxidative N-Heterocyclic Carbene-Catalyzed γ-Carbon Addition of Enals to Imines: Mechanistic Studies and Access to Antimicrobial Compounds.Mechanistic insights into the triazolylidene-catalysed Stetter and benzoin reactions: role of the N-aryl substituent
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P2860
Structures and reactivities of O-methylated Breslow intermediates.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年学术文章
@wuu
2012年学术文章
@zh-cn
2012年学术文章
@zh-hans
2012年学术文章
@zh-my
2012年学术文章
@zh-sg
2012年學術文章
@yue
2012年學術文章
@zh
2012年學術文章
@zh-hant
name
Structures and reactivities of O-methylated Breslow intermediates.
@en
Structures and reactivities of O-methylated Breslow intermediates.
@nl
type
label
Structures and reactivities of O-methylated Breslow intermediates.
@en
Structures and reactivities of O-methylated Breslow intermediates.
@nl
prefLabel
Structures and reactivities of O-methylated Breslow intermediates.
@en
Structures and reactivities of O-methylated Breslow intermediates.
@nl
P2860
P356
P1476
Structures and reactivities of O-methylated Breslow intermediates
@en
P2093
Herbert Mayr
P2860
P304
10408-10412
P356
10.1002/ANIE.201204524
P407
P50
P577
2012-09-11T00:00:00Z