Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.
about
Biochemistry and theory of proton-coupled electron transferStructure and Mechanism of the Diiron Benzoyl-Coenzyme A Epoxidase BoxBEnzymatic oxidation of methaneNitric oxide activation by distal redox modulation in tetranuclear iron nitrosyl complexesIntramolecular C-H and C-F Bond Oxygenation Mediated by a Putative Terminal Oxo Species in Tetranuclear Iron ComplexesDesign and synthesis of a dinucleating ligand system with varying terminal donor functions that provides no bridging donor and its application to the synthesis of a series of Fe(III)-μ-O-Fe(III) complexes.Accelerated Oxygen Atom Transfer and C-H Bond Oxygenation by Remote Redox Changes in Fe3 Mn-Iodosobenzene Adducts.Mössbauer, electron paramagnetic resonance, and density functional theory studies of synthetic S = 1/2 Fe(III)-O-Fe(IV)═O complexes. Superexchange-mediated spin transition at the Fe(IV)═O site.Study of iron dimers reveals angular dependence of valence-to-core X-ray emission spectra.Understanding hydrogen atom transfer: from bond strengths to Marcus theory.Nonheme oxo-iron(IV) intermediates form an oxyl radical upon approaching the C-H bond activation transition state.Dioxygen activation in soluble methane monooxygenaseModeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.High-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe(IV)=O Complexes.Triggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by Ru(II) photocatalysis.A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site.Substrate-triggered activation of a synthetic [Fe2(μ-O)2] diamond core for C-H bond cleavage.Rapid C-H bond activation by a monocopper(III)-hydroxide complex.Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): structure, magnetic properties, and catalytic oxidation studies.Structure of the key species in the enzymatic oxidation of methane to methanolEvaluating the identity and diiron core transformations of a (μ-oxo)diiron(III) complex supported by electron-rich tris(pyridyl-2-methyl)amine ligands.Toward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes.The Q, Compound Q is Finally DecipheredMagnetic circular dichroism and computational study of mononuclear and dinuclear iron(IV) complexes.Protonation of a peroxodiiron(III) complex and conversion to a diiron(III/IV) intermediate: implications for proton-assisted O-O bond cleavage in nonheme diiron enzymes.1H-ENDOR evidence for a hydrogen-bonding interaction that modulates the reactivity of a nonheme Fe(IV)═O unit.A Mononuclear Carboxylate-Rich Oxoiron(IV) Complex: a Structural and Functional Mimic of TauD Intermediate 'J'Triptycene-based Bis(benzimidazole) Carboxylate-Bridged Biomimetic Diiron(II) Complexes.Hydrogen-bonding effects on the reactivity of [X-Fe(III)-O-Fe(IV)═O] (X = OH, F) complexes toward C-H bond cleavage.Dichotomous hydrogen atom transfer vs proton-coupled electron transfer during activation of X-H bonds (X = C, N, O) by nonheme iron-oxo complexes of variable basicityDo Spin State and Spin Density Affect Hydrogen Atom Transfer Reactivity?Enhanced electron-transfer reactivity of nonheme manganese(IV)-oxo complexes by binding scandium ions.Oxidation of water by a nonhaem diiron(IV) complex via proton-coupled electron transfer.Spectroscopic and theoretical investigation of a complex with an [O═Fe(IV)-O-Fe(IV)═O] core related to methane monooxygenase intermediate Q.Hydrogen-abstraction reactivity patterns from A to Y: the valence bond way.Ligand Field Strength Mediates Electron Delocalization in Octahedral [((H)L)2Fe6(L')m](n+) Clusters.X-ray absorption spectroscopic characterization of the diferric-peroxo intermediate of human deoxyhypusine hydroxylase in the presence of its substrate eIF5aStructure and spin state of nonheme FeIVO complexes depending on temperature: predictive insights from DFT calculations and experiments.Isolation of a 2-hydroxytetrahydrofuran complex from copper-promoted hydroxylation of THF.An oxygenase that forms and deoxygenates toxic epoxide.
P2860
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P2860
Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.
@en
type
label
Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.
@en
prefLabel
Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.
@en
P2093
P2860
P356
P1433
P1476
Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.
@en
P2093
Eckard Münck
Genqiang Xue
Lawrence Que
Raymond De Hont
P2860
P2888
P304
P356
10.1038/NCHEM.586
P577
2010-03-21T00:00:00Z