Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents.
about
Recent advances in copper-catalyzed asymmetric coupling reactionsEnantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsCatalytic enantioselective synthesis of quaternary carbon stereocentresPalladium-catalyzed enantioselective Heck alkenylation of acyclic alkenols using a redox-relay strategy.Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers.A broadly applicable NHC-Cu-catalyzed approach for efficient, site-, and enantioselective coupling of readily accessible (pinacolato)alkenylboron compounds to allylic phosphates and applications to natural product synthesis.C-C bond formation via copper-catalyzed conjugate addition reactions to enones in water at room temperatureCatalytic SN2'- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis.Enantioselective Nickel-Catalyzed Intramolecular Allylic Alkenylations Enabled by Reversible Alkenylnickel E/Z Isomerization.Enantioselective allylic alkylation of stereodefined polysubstituted copper enolates as an entry to acyclic quaternary carbon stereocentres.Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron-substituted allylcopper complexes and their in situ site-, diastereo-, and enantioselective additions to aldehydes and ketones.Catalytic enantioselective protoboration of disubstituted allenes. Access to alkenylboron compounds in high enantiomeric purity.A powerful hydrogen-bond-donating organocatalyst for the enantioselective intramolecular oxa-Michael reaction of α,β-unsaturated amides and esters.Construction of quaternary stereogenic carbon centers through copper-catalyzed enantioselective allylic cross-coupling with alkylboranes.Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis.Versatile Homoallylic Boronates by Chemo-, SN 2'-, Diastereo- and Enantioselective Catalytic Sequence of Cu-H Addition to Vinyl-B(pin)/Allylic Substitution.Synthesis of Branched Alkylboronates by Copper-Catalyzed Allylic Substitution Reactions of Allylic Chlorides with 1,1-Diborylalkanes.Copper-free asymmetric allylic alkylation of trisubstituted cyclic allyl bromides using Grignard reagents.
P2860
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P2860
Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
Copper-catalyzed enantioselect ...... ontaining vinylboron reagents.
@en
type
label
Copper-catalyzed enantioselect ...... ontaining vinylboron reagents.
@en
prefLabel
Copper-catalyzed enantioselect ...... ontaining vinylboron reagents.
@en
P2860
P356
P1476
Copper-catalyzed enantioselect ...... ontaining vinylboron reagents.
@en
P2093
James L Carr
P2860
P304
P356
10.1002/ANIE.201202856
P407
P577
2012-05-25T00:00:00Z