Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors

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Copper(i)-catalysed asymmetric allylic reductions with hydrosilanes.

P2860

Q50092604-E97447F4-5ABC-4039-8B29-7498FA723F39

P2860

Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors

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http://www.wikidata.org/entity/Q59203339

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im Mai 2015 veröffentlichter wissenschaftlicher Artikel

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scientific article published on 12 May 2015

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wetenschappelijk artikel

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наукова стаття, опублікована в травні 2015

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Asymmetric Catalysis with Sili ...... stitution of Linear Precursors

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Asymmetric Catalysis with Sili ...... stitution of Linear Precursors

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Asymmetric Catalysis with Sili ...... stitution of Linear Precursors

@en

Asymmetric Catalysis with Sili ...... stitution of Linear Precursors

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Asymmetric Catalysis with Sili ...... stitution of Linear Precursors

@en

Asymmetric Catalysis with Sili ...... stitution of Linear Precursors

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P1476

Asymmetric catalysis with sili ...... stitution of linear precursors

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P2093

Alexander Hensel

http://www.w3.org/2001/XMLSchema#string

P2860

Enantioselective conjugate silyl additions to cyclic and acyclic unsaturated carbonyls catalyzed by Cu complexes of chiral N-heterocyclic carbenes

Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.

Quaternary carbon stereogenic centers through copper-catalyzed enantioselective allylic substitutions with readily accessible aryl- or heteroaryllithium reagents and aluminum chlorides.

Enantioselective synthesis of alkyne-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution reactions with (i-Bu)2(alkynyl)aluminum reagents.

NHC-Cu-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes.

SmI2-mediated radical cyclizations directed by a C-Si bond.

Copper-catalyzed addition of nucleophilic silicon to aldehydes.

Asymmetric synthesis of α-chiral allylic silanes by enantioconvergent γ-selective copper(I)-catalyzed allylic silylation.

Highly site- and enantioselective Cu-catalyzed allylic alkylation reactions with easily accessible vinylaluminum reagents.

Silylzincation of carbon-carbon multiple bonds revisited.

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9062-9065

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scholarly article

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10.1002/CHEM.201501371

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English

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http://www.w3.org/2001/XMLSchema#string

P478

http://www.w3.org/2001/XMLSchema#string

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Martin Oestreich

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2015-05-12T00:00:00Z

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P698

25965581

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Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors

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P2860

P2860

Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors

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type

label

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P1433

P1476

P2093

P2860

P304

P31

P356

P407

P433

P478

P50

P577

P698

P356

P1433

P1476

P2093

P2860

P304

P31

P356

P407

P433

P478

P50

P577

P698