Catalytic asymmetric intermolecular Stetter reaction of enals with nitroalkenes: enhancement of catalytic efficiency through bifunctional additives.
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Organocatalytic Reactions Enabled by N-Heterocyclic CarbenesDiversity-oriented synthesis of drug-like macrocyclic scaffolds using an orthogonal organo- and metal catalysis strategy.Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst.Catalytic enantioselective addition of organoboron reagents to fluoroketones controlled by electrostatic interactions.A continuum of progress: applications of N-hetereocyclic carbene catalysis in total synthesis.Asymmetric homoenolate additions to acyl phosphonates through rational design of a tailored N-heterocyclic carbene catalyst.The effect of the N-mesityl group in NHC-catalyzed reactions.Asymmetric synthesis of cyclopentanes bearing four contiguous stereocenters via an NHC-catalyzed Michael/Michael/esterification domino reaction.Rate and equilibrium constants for the addition of N-heterocyclic carbenes into benzaldehydes: a remarkable 2-substituent effect.A photoisomerization-coupled asymmetric Stetter reaction: application to the total synthesis of three diastereomers of (-)-cephalimysin A.Asymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams.Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect.SNAr-Derived Decomposition By-products Involving Pentafluorophenyl Triazolium Carbenes.N-heterocyclic carbene and Brønsted acid cooperative catalysis: asymmetric synthesis of trans-γ-lactams.Enantioselective N-heterocyclic carbene-catalyzed β-hydroxylation of enals using nitroarenes: an atom transfer reaction that proceeds via single electron transfer.Controlled β-protonation and [4+2] cycloaddition of enals and chalcones via N-heterocyclic carbene/acid catalysis: toward substrate independent reaction control.Asymmetric Stetter reactions catalyzed by thiamine diphosphate-dependent enzymes.Sigmatropic proton shifts: a quantum chemical study.Insights into N-Heterocyclic Carbene-Catalyzed [4+2] Annulation Reaction of Enals with Nitroalkenes: Mechanisms, Origin of Chemo- and Stereoselectivity, and Role of Catalyst.Switchable selectivity in an NHC-catalysed dearomatizing annulation reaction.Electrophilic Activation of Iodonium Ylides by Halogen-Bond-Donor Catalysis for Cross-Enolate Coupling.NHC-catalyzed oxidative γ-addition of α,β-unsaturated aldehydes to isatins: a high-efficiency synthesis of spirocyclic oxindole-dihydropyranones.N-Heterocyclic carbene-catalyzed stereoselective construction of olefinic carbon-sulfur bonds via cross-coupling reaction of gem-difluoroalkenes and thiols.Conjugate umpolung of β,β-disubstituted enals by dual catalysis with an N-heterocyclic carbene and a Brønsted acid: facile construction of contiguous quaternary stereocenters.N-heterocyclic carbene catalyzed homoenolate-addition reaction of enals and nitroalkenes: asymmetric synthesis of 5-carbon-synthon δ-nitroesters.Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2.Enantioselective Stetter reactions of enals and modified chalcones catalyzed by N-heterocyclic carbenes.A case study of proton shuttling in palladium catalysis.Highly Enantioselective Intermolecular Stetter Reaction of Simple Acrylates: Synthesis of α-Chiral γ-KetoestersEvolution of asymmetric organocatalysis: multi- and retrocatalysisMechanistic insights into the triazolylidene-catalysed Stetter and benzoin reactions: role of the N-aryl substituent
P2860
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P2860
Catalytic asymmetric intermolecular Stetter reaction of enals with nitroalkenes: enhancement of catalytic efficiency through bifunctional additives.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Catalytic asymmetric intermole ...... hrough bifunctional additives.
@en
Catalytic asymmetric intermole ...... hrough bifunctional additives.
@nl
type
label
Catalytic asymmetric intermole ...... hrough bifunctional additives.
@en
Catalytic asymmetric intermole ...... hrough bifunctional additives.
@nl
prefLabel
Catalytic asymmetric intermole ...... hrough bifunctional additives.
@en
Catalytic asymmetric intermole ...... hrough bifunctional additives.
@nl
P2860
P356
P1476
Catalytic asymmetric intermole ...... hrough bifunctional additives.
@en
P2093
Daniel A DiRocco
P2860
P304
10402-10405
P356
10.1021/JA203810B
P407
P577
2011-06-16T00:00:00Z