C-H bond cleavage with reductants: re-investigating the reactivity of monomeric Mn(III/IV)-oxo complexes and the role of oxo ligand basicity.
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Proton-coupled electron transferThermochemistry of proton-coupled electron transfer reagents and its implicationsInsight into the mechanism of an iron dioxygenase by resolution of steps following the FeIV=HO speciesAccelerated Oxygen Atom Transfer and C-H Bond Oxygenation by Remote Redox Changes in Fe3 Mn-Iodosobenzene Adducts.Efficient C-H Bond Activations via O2 Cleavage by a Dianionic Cobalt(II) ComplexPreparation and Properties of an MnIV-Hydroxide Complex: Proton and Electron Transfer at a Mononuclear Manganese Site and its Relationship to the Oxygen Evolving Complex within Photosystem IIIron(IV)hydroxide pK(a) and the role of thiolate ligation in C-H bond activation by cytochrome P450Rapid C-H bond activation by a monocopper(III)-hydroxide complex.Preparation and properties of a monomeric high-spin Mn(V)-oxo complex.Dichotomous hydrogen atom transfer vs proton-coupled electron transfer during activation of X-H bonds (X = C, N, O) by nonheme iron-oxo complexes of variable basicityReactivities of Fe(IV) complexes with oxo, hydroxo, and alkylperoxo ligands: an experimental and computational study.High-valent iron and manganese complexes of corrole and porphyrin in atom transfer and dioxygen evolving catalysis.Role of metal-oxo complexes in the cleavage of C-H bonds.The reactivity of the active metal oxo and hydroxo intermediates and their implications in oxidations.Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes.Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities.Metal-Templated Ligand Architectures for Trinuclear Chemistry: Tricopper Complexes and Their O2 Reactivity.Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.Hydrogen atom abstraction from hydrocarbons by a copper(III)-hydroxide complexRole of the secondary coordination sphere in metal-mediated dioxygen activation.Synthesis and characterization of a series of structurally and electronically diverse Fe(II) complexes featuring a family of triphenylamido-amine ligands.Catalytic reduction of dioxygen to water with a monomeric manganese complex at room temperature.Formation, structure, and EPR detection of a high spin Fe(IV)-oxo species derived from either an Fe(III)-oxo or Fe(III)-OH complex.Tautomerisation and hydrogen-bonding interactions in four-coordinate metal halide and azide complexes of N-donor-extended dipyrromethanes.Electronic tuning of iron-oxo-mediated C-H activation: effect of electron-donating ligand on selectivity.Theoretical studies on concerted versus two steps hydrogen atom transfer reaction by non-heme Mn(IV/III)=O complexes: how important is the oxo ligand basicity in the C-H activation step?Direct Comparison of C-H Bond Amination Efficacy through Manipulation of Nitrogen-Valence Centered Redox: Imido versus Iminyl.Control of Product Distribution and Mechanism by Ligation and Electric Field in the Thermal Activation of Methane.Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with FeV═O and FeIV═O Units.Equatorial Ligand Perturbations Influence the Reactivity of Manganese(IV)-Oxo Complexes.Activation parameters as mechanistic probes in the TAML iron(V)-oxo oxidations of hydrocarbons.Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins.Robust and efficient amide-based nonheme manganese(III) hydrocarbon oxidation catalysts: substrate and solvent effects on involvement and partition of multiple active oxidants.Formation and characterization of a reactive chromium(v)-oxo complex: mechanistic insight into hydrogen-atom transfer reactions.Double N–H bond activation of N,N′-bis-substituted hydrazines with stable N-heterocyclic silylene
P2860
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P2860
C-H bond cleavage with reductants: re-investigating the reactivity of monomeric Mn(III/IV)-oxo complexes and the role of oxo ligand basicity.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
2009年论文
@zh
2009年论文
@zh-cn
name
C-H bond cleavage with reductants: re-investigating the reactivity of monomeric Mn
@nl
C-H bond cleavage with reducta ...... e role of oxo ligand basicity.
@en
type
label
C-H bond cleavage with reductants: re-investigating the reactivity of monomeric Mn
@nl
C-H bond cleavage with reducta ...... e role of oxo ligand basicity.
@en
prefLabel
C-H bond cleavage with reductants: re-investigating the reactivity of monomeric Mn
@nl
C-H bond cleavage with reducta ...... e role of oxo ligand basicity.
@en
P2093
P2860
P356
P1476
C-H bond cleavage with reducta ...... e role of oxo ligand basicity.
@en
P2093
A S Borovik
Meng-Yin Yang
Trenton H Parsell
P2860
P304
P356
10.1021/JA8100825
P407
P577
2009-03-01T00:00:00Z