Highly site- and enantioselective Cu-catalyzed allylic alkylation reactions with easily accessible vinylaluminum reagents.
about
Organocatalytic Reactions Enabled by N-Heterocyclic CarbenesEnantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsChiral Bidentate NHC Ligands Based on the 1,1'-Binaphthyl Scaffold: Synthesis and Application in Transition-Metal-Catalyzed Asymmetric Reactions.Catalytic enantioselective olefin metathesis in natural product synthesis. Chiral metal-based complexes that deliver high enantioselectivity and moreEnantioselective CuH-Catalyzed Hydroallylation of Vinylarenes.Synthesis of Pd Complexes Bearing an Enantiomerically-Resolved Seven-Membered N-Heterocyclic Carbene Ligands and Initial Studies of their Use in Asymmetric Wacker-Type Oxidative Cyclization ReactionsA broadly applicable NHC-Cu-catalyzed approach for efficient, site-, and enantioselective coupling of readily accessible (pinacolato)alkenylboron compounds to allylic phosphates and applications to natural product synthesis.Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications.Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity.Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles.Enantioselective Nickel-Catalyzed Intramolecular Allylic Alkenylations Enabled by Reversible Alkenylnickel E/Z Isomerization.Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents.Stereogenic-at-metal Zn- and Al-based N-heterocyclic carbene (NHC) complexes as bifunctional catalysts in Cu-free enantioselective allylic alkylations.Enantioselective synthesis of alkyne-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution reactions with (i-Bu)2(alkynyl)aluminum reagents.Vicinal diboronates in high enantiomeric purity through tandem site-selective NHC-Cu-catalyzed boron-copper additions to terminal alkynes.Enantioselective synthesis of allylboronates bearing a tertiary or quaternary B-substituted stereogenic carbon by NHC-Cu-catalyzed substitution reactions.Alpha-selective Ni-catalyzed hydroalumination of aryl- and alkyl-substituted terminal alkynes: practical syntheses of internal vinyl aluminums, halides, or boronates.Combining NHC-Cu and Brønsted base catalysis: enantioselective allylic substitution/conjugate additions with alkynylaluminum reagents and stereospecific isomerization of the products to trisubstituted allenes.Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.2-[(Di-methyl-phenyl-phosphanyl-idene)aza-nium-yl]-5-methyl-benzene-sulfonate benzene monosolvate.Enantioselective synthesis of all-carbon quaternary stereogenic centers by catalytic asymmetric conjugate additions of alkyl and aryl aluminum reagents to five-, six-, and seven-membered-ring beta-substituted cyclic enones.Enantiospecific, nickel-catalyzed cross-couplings of allylic pivalates and arylboroxines.A cooperative N-heterocyclic carbene/chiral phosphate catalysis system for allenolate annulations.Stereoisomerically pure trisubstituted vinylaluminum reagents and their utility in copper-catalyzed enantioselective synthesis of 1,4-dienes containing Z or E alkenes.Enantioselective total synthesis of clavirolide C. Applications of Cu-catalyzed asymmetric conjugate additions and Ru-catalyzed ring-closing metathesis.Copper-free asymmetric allylic alkylation with a Grignard reagent: design of the ligand and mechanistic studies.Bidentate hydroxyalkyl NHC ligands for the copper-catalyzed asymmetric allylic substitution of allyl phosphates with Grignard reagents.Copper-catalyzed regioselective fluorination of allylic halides.Cu-Catalyzed electrophilic amination of internal alkynes via hydroalumination.Photocatalytic Aerobic Phosphatation of Alkenes.Ligand-Controlled Regiodivergent and Enantioselective Copper-Catalyzed Hydroallylation of Alkynes.Copper(i)-catalysed asymmetric allylic reductions with hydrosilanes.Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates.Copper-free asymmetric allylic alkylation of trisubstituted cyclic allyl bromides using Grignard reagents.Nickel-Catalyzed Cross-Coupling of Aryl Bromides with Tertiary Grignard Reagents Utilizing Donor-Functionalized N-Heterocyclic Carbenes (NHCs)Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors
P2860
Q28081119-51D58F65-42B3-4524-BC94-C82B9BB92D3EQ36049587-95E764C4-42FB-47B8-A649-4579E1DD45C4Q36144135-28569D95-1BE0-44BA-B86C-02DC49780E13Q36452747-C5C4C15C-44CB-4F06-812B-8A25C8B63843Q36852041-16139702-9F83-4B21-9109-07802072C7DCQ37234847-6132ABF0-F2A3-4363-86B7-B16D07739486Q38274670-1C71E4B1-C2F7-4B2D-9F0F-9484A1BEEB19Q39084928-2A6F8D73-B44A-4723-A546-3E31B65877C4Q40433430-19A8F599-8E3D-4E48-86B1-58ED423B7E76Q40700153-84015721-33C7-4B4A-817E-3959C59B60AFQ40761823-E2A9FA8F-79F2-4620-B44F-0E9A1720DF17Q40950927-548D40C4-6C1D-4DDC-AC8D-0BCD1459B125Q41823171-CA87448A-B4C7-4803-AD89-101A56550001Q41837498-929BEAC3-78DA-41D5-B2CB-3CB2D5D89BAEQ41838586-F9E3150F-E019-4BC6-8F75-E9E33E3E9ED2Q41869714-2F9EE531-2C86-46C3-9F10-039151AFBDD4Q41917175-DF3D017A-1237-45F5-88CC-AFDEBFBD8772Q41968609-9ED3C47E-9F3F-4ED1-9B36-6B4EECFAA499Q41998174-82FD6324-3516-4A43-BA35-CE478E554B31Q42114279-64DEEC23-275E-4DA1-A6ED-CAC82EA4B1EBQ42160929-40F1B622-37CD-4172-A4F9-7E6E57C20E38Q42545726-BFD662EA-5BDF-4DE8-9AEF-DE3AA618559BQ42723211-9C244197-E065-4C01-BB3D-2535A74694DDQ42837159-77E0D5A9-A418-4CE5-A96F-EF60EAC64AF7Q42872334-AC92348B-626D-454F-9768-26E1E63364EBQ43196623-811013E2-14D7-4191-B60B-2196A6860A61Q43476954-5B4FF5E8-F1B9-410D-A44F-582029CE97EAQ44008853-20514525-FA62-443A-AEB1-3EC5AAF1F6BFQ44295386-8C4E90C2-2442-4307-A77A-09101E775FC0Q48121137-9679A5B2-A139-40EE-A7AE-CA619D110C1CQ48152931-4607DA26-B390-45A6-8C2B-1932593FDE85Q48189135-F3AC4AB4-785C-4A07-92A6-1F647D7EBEF9Q50092604-91FE0A27-CA5F-4E65-8837-CB6DC0CEA6FDQ51010518-E0FCB050-07E2-4E22-AF24-BEFCC8906442Q54427371-FB5A1306-0A5E-4F2F-90BA-9F69AF25FD56Q57657351-16113BBB-517A-4124-9FB0-A01570F76E55Q59203339-EF471906-C17B-48C1-8E41-9F5361E1D113
P2860
Highly site- and enantioselective Cu-catalyzed allylic alkylation reactions with easily accessible vinylaluminum reagents.
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年学术文章
@wuu
2007年学术文章
@zh-cn
2007年学术文章
@zh-hans
2007年学术文章
@zh-my
2007年学术文章
@zh-sg
2007年學術文章
@yue
2007年學術文章
@zh
2007年學術文章
@zh-hant
name
Highly site- and enantioselect ...... ssible vinylaluminum reagents.
@en
Highly site- and enantioselect ...... ssible vinylaluminum reagents.
@nl
type
label
Highly site- and enantioselect ...... ssible vinylaluminum reagents.
@en
Highly site- and enantioselect ...... ssible vinylaluminum reagents.
@nl
prefLabel
Highly site- and enantioselect ...... ssible vinylaluminum reagents.
@en
Highly site- and enantioselect ...... ssible vinylaluminum reagents.
@nl
P2093
P356
P1476
Highly site- and enantioselect ...... ssible vinylaluminum reagents.
@en
P2093
Dennis G Gillingham
Katsuhiro Akiyama
M Kevin Brown
P304
P356
10.1021/JA0782192
P407
P577
2007-12-19T00:00:00Z