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Quaternary chiral β(2,2)-amino acids with pyridinium and imidazolium substituents.Chemical behaviour of a prototype boryl(phosphino)carbene.Water-soluble triazabutadienes that release diazonium species upon protonation under physiologically relevant conditions.Carbenes as catalysts for transformations of organometallic iron complexes.The ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.Designing N-heterocyclic carbenes: simultaneous enhancement of reactivity and enantioselectivity in the asymmetric hydroacylation of cyclopropenes.Intermolecular Cross-Acyloin Reactions by Fluoride-Promoted Additions of O-Silyl Thiazolium Carbinols.3,3'-Dibenzyl-1,1'-(2,4,6-trimethyl-m-phenyl-enedimethyl-ene)diimidazol-3-ium dibromide.Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene.A new library of arsine, stibine-stabilized N-heterocyclic carbene palladium complexes: synthesis, structures and activities in C-C and C-N coupling reactions.Oxidative N-heterocyclic carbene catalyzed stereoselective annulation of simple aldehydes and 5-alkenyl thiazolones.Reversed-Polarity Synthesis of Diaryl Ketones through Palladium-Catalyzed Direct Arylation of 2-Aryl-1,3-dithianes.Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst.Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.A facile synthetic route to benzimidazolium salts bearing bulky aromatic N-substituents.Direct estimate of the internal π-donation to the carbene centre within N-heterocyclic carbenes and related moleculesOne-carbon extrusion from a tetraazafulvalene. Isolation of aldehydes and a study of their origin.Synthesis of the tetracyclic core of Illicium sesquiterpenes using an organocatalyzed asymmetric Robinson annulation.A dual Lewis base activation strategy for enantioselective carbene-catalyzed annulations.Carbene catalystsRecent advances in the chemistry and biology of naturally occurring antibiotics.Impact of solvent polarity on N-heterocyclic carbene-catalyzed beta-protonations of homoenolate equivalentsNeurotrophic natural products: chemistry and biology.1-Ethyl-3-methylimidazolium acetate as a highly efficient organocatalyst for cyanosilylation of carbonyl compounds with trimethylsilyl cyanide.Stable cyclic carbenes and related species beyond diaminocarbenes.Nitrogen-rich azoles as ligand spacers in coordination polymers.Synthesis and reactions of N-heterocyclic carbene boranes.Fluorine conformational effects in organocatalysis: an emerging strategy for molecular design.Advances in metal-carbene complexes as potent anti-cancer agents.A continuum of progress: applications of N-hetereocyclic carbene catalysis in total synthesis.Synthesis and application of water-soluble NHC transition-metal complexes.Combining transition metal catalysis and organocatalysis--an update.N-Heterocyclic carbenes (NHCs) as organocatalysts and structural components in metal-free polymer synthesis.Nano-magnetite (Fe3O4) as a support for recyclable catalysts in the development of sustainable methodologies.Imidazolium salts and their polymeric materials for biological applications.Catalytic asymmetric synthesis of enantioenriched heterocycles bearing a C-CF3 stereogenic center.Acetaldehyde: A Small Organic Molecule with Big Impact on Organocatalytic Reactions.Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal ComplexesScope and limitations of the dual-gold-catalysed hydrophenoxylation of alkynes.Recent advances in N-heterocyclic carbene catalyzed achiral synthesis.
P2860
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P2860
description
scientific article published on 01 January 2007
@en
wetenschappelijk artikel
@nl
наукова стаття, опублікована у квітні 2007
@uk
name
N-Heterocyclic Carbenes as Organocatalysts
@en
N-Heterocyclic Carbenes as Organocatalysts
@nl
type
label
N-Heterocyclic Carbenes as Organocatalysts
@en
N-Heterocyclic Carbenes as Organocatalysts
@nl
prefLabel
N-Heterocyclic Carbenes as Organocatalysts
@en
N-Heterocyclic Carbenes as Organocatalysts
@nl
P356
P1476
N-heterocyclic carbenes as organocatalysts
@en
P2093
Nicolas Marion
Silvia Díez-González
P304
P356
10.1002/ANIE.200603380
P407
P577
2007-01-01T00:00:00Z